The cleaning solutions augmented with tetraalkylammonium hydroxides ͑TAAHs͒ with various chain-lengths of hydrocarbon substituents were developed for post-poly-Si chemical mechanical polishing ͑CMP͒ cleaning. The cleaning performance with respect to particle, organic, and metal removal as well as surface roughness was evaluated for a series of 3% NH 4 OH solutions dosed with 0.26 M of a TAAH and 100 ppm of ethylenediaminetetraacetic acid ͑EDTA͒. The experimental results demonstrated that the cleaning solutions enhanced with these surfactants ͑TAAH͒ and a chelating agent ͑EDTA͒ achieved significantly better removal efficiencies of particle and metal impurities than the control solution containing 3% NH 4 OH only. A conceptual model involving surface adsorption and double-layer formation was used to postulate the aqueous-phase surface interactions between the tetraalkylammonium cations and the poly-Si surface, and to explain the removal mechanisms of particle and metal impurities from the surface. The improved electrical properties ͑current density-electric field and charge-to-breakdown characteristics͒ of the post-CMP capacitor after cleaning further demonstrated the reliability and feasibility of the proposed cleaning recipes.The increasing complexity and miniaturization of modern integrated circuits demand a high device yield, meaning that lower defect density in the active region of silicon devices is a necessity. 1,2 For instance, the reliability of nonvolatile memory devices such as EEPROM, EPROM ͑electrically erasable and erasable programmable read-only memory, respectively͒, and flash memory is strongly dependent on the polyoxide quality characterized by low leakage current and high breakdown electrical field to prolong their data retention capabilities. Inadequate control over the thickness uniformity and surface roughness of the poly-Si layer directly leads to defect formation on the poly-Si/polyoxide interface, thus severely degrading the electrical properties. In recent years, the chemical mechanical polishing ͑CMP͒ process has been widely accepted as the mainstream planarization technique in the fabrication of deep submicrometer integrated circuits 3 in light of its capability to reduce surface roughness. However, as the device's dimension continues to scale down, the requirement for post-CMP cleaning becomes increasingly more stringent to ensure high device yield.The brush-scrubbing technique in combination with dilute ammonium hydroxide solution has been employed for many years and was considered among the most effective methods for removing particles after the CMP process. 4 Numerous studies focusing on improving oxide layer CMP as well as the post-CMP cleaning efficiency have been reported. 5-9 Jolley 7 reported that the solution containing tetramethylammonium hydroxide ͑TMAH͒ showed enhancement of metal removal, and had little effect on the surface roughness for post tungsten-CMP cleaning as compared to ammonium hydroxide solution. Cady and Varadarajan 8 also proposed that the alkaline solution co...