Charge transfer in steam purified arc discharge single walled carbon nanotubes filled with lutetium halides

Abstract

In the present work, the effect of doping on electronic properties in bulk purified and filled arc-discharge single-walled carbon nanotubes samples is studied for the first time by in situ Raman spectroelectrochemical method.

Spectroscopy of Filled Single-Walled Carbon Nanotubes

“…Raman spectroscopy was applied to investigate the modified electronic structure of SWCNTs filled with MnCl 2 , MnBr 2 [ 35 , 36 ], FeCl 2 , FeBr 2 , FeI 2 [ 12 ], CoBr 2 [ 13 ], NiCl 2 , NiBr 2 [ 37 ], ZnCl 2 [ 20 ], ZnCl 2 , ZnBr 2 , ZnI 2 [ 14 ], AgCl, AgBr, AgI [ 15 ], AgCl [ 38 , 39 ], CuCl [ 17 ], CuI [ 40 , 41 ], CuCl, CuBr, CuI [ 18 ], CdCl 2 [ 20 , 42 ], CdCl 2 , CdBr 2 , CdI 2 [ 16 ], PbCl 2 , PbBr 2 , PbI 2 [ 43 ], SnF 2 [ 44 ], RbI [ 45 ], RbAg 4 I 5 [ 46 ], TbCl 3 [ 20 , 47 , 48 ], TbBr 3 , TbI 3 [ 48 ], TmCl 3 [ 24 , 47 ], PrCl 3 [ 19 , 47 ], LuCl 3 , LuBr 3 , LuI 3 [ 49 ], HgCl 2 [ 50 ], GaSe, GaTe [ 21 , 22 ], SnS, SnTe [ 22 , 23 ], Bi 2 Se 3 [ 22 ] and Bi 2 Te 3 [ 24 ], Ag […”

Phemenology of Filling, Investigation of Growth Kinetics and Electronic Properties for Applications of Filled Single-Walled Carbon Nanotubes

“…Metal halogenides and metal chalcogenides were filled inside SWCNTs in 60 papers [ 154 , 155 , 156 , 157 , 158 , 159 , 160 , 161 , 162 , 163 , 164 , 165 , 166 , 167 , 168 , 169 , 170 , 171 , 172 , 173 , 174 , 175 , 176 , 177 , 178 , 179 , 180 , 181 , 182 , 183 , 184 , 185 , 186 , 187 , 188 , 189 , 190 , 191 , 192 , 193 , 194 , 195 , 196 , 197 , 198 , 199 , 200 , 201 , 202 , 203 , 204 ,…”

Metal and Metal Halogenide-Filled Single-Walled Carbon Nanotubes: Kinetics, Electronic Properties, Engineering the Fermi Level

“…The most popular among them are metal halogenides. SWCNTs were filled with metal fluorides (SnF 2 [ 122 ]), metal chlorides (sodium/cesium/copper/silver/tantal)Cl [ 113 , 123 , 124 , 125 , 126 , 127 , 128 , 129 , 130 , 131 , 132 , 133 ], (manganese/iron/cobalt/nickel/zinc/cadmium/mercury/palladium/lead)Cl 2 [ 108 , 126 , 127 , 134 , 135 , 136 , 137 , 138 , 139 , 140 , 141 , 142 , 143 , 144 , 145 ], (iron/yttrium/ruthenium/gold/lanthan/neodym/samarium/europium/gadolinium/terbium/thulium/praseodymium/holmium/erbium/ytterbium/luthetium)Cl 3 , Al 2 Cl 6 [ 102 , 103 , 107 , 108 , 121 , 126 , 127 , 134 , 139 , 142 , 146 , 147 , 148 , 149 , 150 , 151 , 152 ], (zirkonium/hafnium/platinum/thorium)Cl 4 [ 108 …”

“…Raman spectroscopy was applied for manganese halogenides [ 136 , 143 ], iron halogenides [ 138 ], CoBr 2 [ 158 ], nickel halogenides [ 135 ], ZnCl 2 [ 142 ], zinc halogenides [ 137 ], silver halogenides [ 123 ], CuCl [ 129 ], CuI [ 161 , 165 ], copper halogenides [ 124 ], CdCl 2 [ 142 , 144 ], cadmium halogenides [ 141 ], lead halogenides [ 145 ], SnF 2 [ 122 ], RbI [ 168 ], RbAg 4 I 5 [ 175 ], TbCl 3 [ 142 , 149 , 151 ], TbBr 3 , TbI 3 [ 151 ], TmCl 3 [ 149 , 179 ], PrCl 3 [ 149 , 150 ], luthetium halogenides [ 152 ], and HgCl 2 [ 140 ].…”