1987
DOI: 10.1021/ic00272a030
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Charge-transfer absorption and emission of Cu(NN)2+ systems

Abstract: Supplementary Material Available: Tables of coordinates and isotropic thermal parameters for hydrogen atoms and anisotropic thermal parameters (2 pages); listings of observed and calculated structure factors (14 pages). Ordering information is given on any current masthead page.

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Cited by 171 publications
(162 citation statements)
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“…[3] Substituents at the 2 and 9 positions reduce the degree of excited-state distortion, [3,4] leading to room-temperature emission for most copper(i) complexes of 2,9-disubstituted-1,10-phenanthrolines.…”
Section: A Photoluminescent Copper(i) Complex With An Exceptionally Hmentioning
confidence: 99%
“…[3] Substituents at the 2 and 9 positions reduce the degree of excited-state distortion, [3,4] leading to room-temperature emission for most copper(i) complexes of 2,9-disubstituted-1,10-phenanthrolines.…”
Section: A Photoluminescent Copper(i) Complex With An Exceptionally Hmentioning
confidence: 99%
“…Copper(I) diimine coordination complexes (denoted [Cu I (NN) 2 ] + ) have a long, rich history that parallels that of their transition-metal cousins, polypyridyl ruthenium(II) systems [1][2][3][4][5][6][7][8][9][10][11] . Current interest is driven by a desire to employ transition metal coordination complexes in applications from solar energy conversion 12 to chemical sensing 13,14 and molecular devices.…”
Section: Introductionmentioning
confidence: 99%
“…p ⁄ transitions [52][53][54]. The higher energy region is dominated by an intense UV band at 275 nm for 1 and 2 which is assigned to p ?…”
Section: Characterizationmentioning
confidence: 99%