Motivated by recent experimental research, we study the processes in an ac driven superconducting constriction whereby one quasiparticle is promoted to the delocalized states outside the superconducting gap. We demonstrate that with these processes one can control the population of the Andreev bound states in the constriction. We stress an interesting charge asymmetry of these processes that may produce a charge imbalance of accumulated quasiparticles, which depends on the phase.PACS numbers: 74.40. Gh., 74.50.+r, 74.78.Na Superconducting nanodevices are among the most promising candidates to realize quantum computation in the solid state [1], and for many other applications. Quasiparticle poisoning, whereby an unwanted quasiparticle enters a bound state in the device, is an important factor harming their proper operation [2]. Naively, the superconducting gap ∆ should ensure an exponentially small quasiparticle concentration at low temperatures. However, various experiments indicate that a long-lived, non-equilibrium quasiparticle population persists in the superconductor, affecting the operation of various superconducting devices [3][4][5][6][7][8], including tempting proposals to use Majorana states in superconductors [9][10][11].This makes it important to develop the means of an active control of the quasiparticle population in bound states associated with a nano-device.As a generic model we consider a superconducting constriction with a few highly transparent channels. Such constrictions are made on the basis of atomic break junctions [12]. The simplicity of their theoretical description enabled detailed theoretical research [13][14][15]. In the presence of a phase difference at the constriction, an Andreev bound state (ABS) is formed in each channel [16,17]. In a recent pioneering experiment [18], the population of such a single bound state has been detected by its effect on the supercurrent in the constriction. The spectroscopy of Andreev states has also been successfully performed in this setup [19,20]. Thus motivated, we theoretically investigate the control of the population of quasiparticles in the ABS at a superconducting constriction by means of pulses of high-frequency microwave irradiation.In this Letter, we demonstrate that an efficient control of the ABS can be achieved by inducing the processes of ionization and refill (Fig. 1), due to an ac modulation of the phase drop across the junction, φ(t) = φ+δφ sin(Ωt). In the course of such a process, a quasiparticle is promoted to the delocalized states and leaves the constriction. We compute the rates of these processes in the lowest order in irradiation amplitude δφ. We find an interesting charge asymmetry of the emitted quasiparticles. This asymmetry leads to a net quasiparticle current and charge imbalance of the quasiparticles accumulated in the vicinity of the constriction. Charge imbalance can be measured by a standard setup using a normalsuperconducting (N-S) tunnel junction [21][22][23][24][25].We focus on the regime of low temperatures whi...