Charge-carrier thermalization in bulk and monolayer CdTe from first principles

Abstract

While cadmium telluride (CdTe) thin films are being used in solar cell prototyping for decades, the recent advent of two-dimensional (2D) materials challenges the fundamental limit for thickness of conventional CdTe layers. Here, we report our theoretical predictions on photocarrier dynamics in an ultimately thin (about 1 nm) CdTe slab. It corresponds to a layer that is just a single unit cell thick, when the bulk parent crystal in the zinc blende phase is cleaved along the [110] facet. Using an ab-initio method based on density functional theory (DFT) and the Boltzmann equation in the relaxation time approximation (RTA), we determine the thermalization time for charge carriers excited to a certain energy for instance through laser irradiation. Our calculations include contributions arising from all phonon branches in the first Brillouin zone (BZ), thus capturing all relevant inter-and intraband carrier transitions due to electron-phonon scattering. We find that the photocarrier thermalization time is strongly reduced, by one order of magnitude for holes and by three orders of magnitude for electrons, once the CdTe crystal is thinned down from the bulk to a monolayer. Most surprisingly, the electron thermalization time becomes independent of the electron excess energy up to about 0.5 eV, when counted from the conduction band minimum (CBM). We relate this peculiar behavior to the degenerate and nearly parabolic lowest conduction band that yields a constant density of states in the 2D limit. Our findings may be useful for designing novel CdTe-based optoelectronic devices, which employ nonequilibrium photoexcited carriers to improve the performance.

Thermalization of photoexcited carriers in two-dimensional transition metal dichalcogenides and internal quantum efficiency of van der Waals heterostructures

“…In what follows, we use an approach already applied successfully to bulk and 2D materials [13,42,44,45]. For instance we have demonstrated in our recent work that phonon emission by photocarriers in graphene is strongly suppressed at low excess energies of about 100 meV [13].…”