A map φ on an associative ring is called a multiplicative Lie derivation if φ([x, y]) = [φ(x), y] + [x, φ(y)] holds for any elements x, y, where [x, y] = xy − yx is the Lie product. In the paper, we discuss the multiplicative Lie derivations on the triangular 3-matrix rings T = T3(Ri; Mij). Under the standard assumption QiZ(T )Qi = Z(QiT Qi), i = 1, 2, 3, we show that every multiplicative Lie derivation ϕ : T → T has the standard form ϕ = δ + γ with δ a derivation and γ a center valued map vanishing each commutator.2010 Mathematics Subject Classification. 16W25; 15A78; 47B47.