Starch is a kind of natural, renewable, and degradable carbohydrate, severing as basic metabolic energy provider. Different parts of plants, including seeds, roots, as well as stems, leaves, fruits and even pollens are common sources of starches [1,2]. Modern research on starches from various resources have demonstrated wide applications in food, plastic, adhesive, daily necessities, and pharmaceutical industries due to their distinguished gelling, film forming, and biodegradable properties [3][4][5]. Generally, starch is classified into Rapidly Digestible Starch (RDS), Slowly Digestible Starch (SDS), and Resistant Starch (RS) according to the rate of digestibility in the human body. Specifically, RDS is rapidly digested in the mouth and small intestine, and SDS is completely digested in the small intestine at a comparatively slow rate, while RS is used by microorganisms in the large intestine [6]. The digestibility properties of starch can reflect the nutritional values of food. At present, the major resources of starches in commercial market are maize, cassava, potato, wheat, and rice, which have relatively low contents of RS [7]. With the growing market and industrial demands, exploration of new starches with different physicochemical, structural, and functional properties has been greatly motivated [8][9][10].Pachyrhizus erosus root, also called jicama or yam bean, is a kind of vegetable with crispy and succulent flesh in white or light brown color. It can be eaten both in raw slices and cooked forms. This tropical/subtropical plant in legume family has been cultivated in Mexico since early times, and then being extensively imported to many other countries. It has high productivity and special sensory attributes, but it is underutilized at present [11]. A recent review reported that this un-exploited crop has potential applications in food industry, such as production of monosaccharides, oligosaccharides, high glucose syrups, flour, and wine, and being incorporated in yogurt or other milk products [12]. The tuberous jicama root contains about 80% water, 0.1% lipid, 0.5% ash, 1% protein, 15% carbohydrates, and 9% starch [13]. As a major component of the root, starch has been characterized in many studies [14][15][16][17]. Those starches from Pachyrhizus spp. were found to have small circular and polygonal shapes, and low pasting temperature [12]. At present, there are only a few investigations referring to the physicochemical and functional properties of jicama starches isolated that are widely cultivated in China. Since planting time and development stages