2002
DOI: 10.1016/s0167-2738(02)00729-4
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Characterization of vanadium oxide sol as a starting material for high rate intercalation cathodes

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Cited by 84 publications
(39 citation statements)
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“…Additionally, it is well known that the Li + intercalation/deintercalation response is dependent on the diffusion coefficient of the species; consequently, a large diffusion coefficient will result in a fast response [40]. The diffusion coefficient of APCVD V2O5 estimated in this work is higher than V2O5 grown by atomic layer CVD [41], solution process [42], spin-coating [43], and pulsed spray pyrolysis [44], strengthening the growth of large area electrodes by APCVD with good electrochemical performance. …”
Section: Cyclic Voltammetrymentioning
confidence: 70%
“…Additionally, it is well known that the Li + intercalation/deintercalation response is dependent on the diffusion coefficient of the species; consequently, a large diffusion coefficient will result in a fast response [40]. The diffusion coefficient of APCVD V2O5 estimated in this work is higher than V2O5 grown by atomic layer CVD [41], solution process [42], spin-coating [43], and pulsed spray pyrolysis [44], strengthening the growth of large area electrodes by APCVD with good electrochemical performance. …”
Section: Cyclic Voltammetrymentioning
confidence: 70%
“…In addition, V 2 O 5 has advantages of low cost, abundance and better safety, which make it a promising cathode candidate. However, the practical application of V 2 O 5 has been seriously hindered by the slow lithium-ion diffusion, low electronic conductivity, which leads to poor cycling stability and poor rate capability [6][7][8]. To improve electrochemical performance of the V 2 O 5 electrode, fabricating nanostructured V 2 O 5 materials such as nanofibers [9], nanowires [10] and nanospheres [11][12][13] has become one of the most effective methods to enhance the electrochemical performance due to the improved lithium-ion diffusion and electronic conductivity.…”
Section: Introductionmentioning
confidence: 99%
“…[ 24,25 ] The effects of thin V 2 O 5 layers on conductive materials such as metal fi bers and carbonaceous materials have been studied recently. [26][27][28][29][30] The issue at hand is how to design the electrode structure with a metal oxide rather than choose the oxide material, since most metal oxides provide more-or-less similar pseudocapacitance. Metal oxides have a high resistivity, which is detrimental for high-power capacitance and cycle performance.…”
Section: Introductionmentioning
confidence: 99%