“…The intermolecular and intramolecular vibrational and rotational modes, including fingerprints of saccharides and pesticides, can be identified across the THz spectrum . To overcome the small scattering cross sections of analytes, microstructures, such as metamaterials (including metasurface, − absorber, and hybrid metamaterials , ) and photonic crystals, can be exploited to resonantly enhance the interactions between THz waves and analytes, − thereby improving the sensitivity to enable detection of trace amount of the material and/or molecule. ,, Metals, − dielectrics, and semiconducting materials , have all been utilized to fabricate such microstructures. Typically, once they are fabricated, their spectral responses are fixed unless materials with tunable properties [e.g., two-dimensional (2D) materials, semiconductors, and phase-change materials] are integrated and external stimuli are applied. , Tunable THz photonic microstructures are of great importance in chemical and biological sensing by facilitating spectral overlap between the microstructure resonances and analyte fingerprints.…”