“…A tetragonal phase (Figure 2a), with unit cell parameters a=6.070 Å, c=12.224 Å, c/a=2.0138, and a secondary phase (Figure 2b) taking place in the orthorhombic structure with unit cell parameters a=6.274 Å, b=10.793 Å, c=14.498 Å. Although in a recent work we have shown that polycrystalline Ag(In 1-x Ga x ) 5 Te 8 may exhibit a single tetragonal structure for all x values [9], the presence of these two phases in AgIn 4 GaTe 8 is not surprising, since other authors have report that the ternary AgGa 5 Te 8 can crystallize in both tetragonal and orthorhombic structure [8,13]. The unit cell parameters obtained for the tetragonal phase in our sample depart from the values a=6.1503 Å, c=12.329 Å, and c/a=2.0046, reported for single-tetragonal AgIn 4 GaTe 8 [9].…”