Abstract:Liquid chromatography under limiting conditions of adsorption (LC LCA) can be considered as a new tool to perform, simultaneously, molar mass and composition determination of statistical copolymers and to separate copolymer blends as a function of copolymer composition or microstructure. The suitability of LC LCA has been demonstrated for two series of statistical copolymers, poly(styrene-co-methyl methacrylate), poly(S=MMA), varying either in molar mass or composition. The binary eluent consisted of a mixture… Show more
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