Characterization of polyamide thin film composite membranes incorporated silver nanoparticles

Abstract

In this study, the polyamide thin film composite membrane surface has been modified by anti-microbial silver nanoparticles (AgNPs). The membrane surfaces were interwoven with AgNPs by ultraviolet grafting polymerization method using AgNPs with or without poly(ethylene glycol) (PEG). The membrane surface characteristics were determined by scanning electron microscopy-energy dispersive x-ray spectrometry images, attenuated total reflection-Fourier transforms infrared spectroscopy, water contact angle values, and anti-bacterial property. The separation performance was determined based on the flux and the ability to remove calcium ions in water. The anti-biofouling property was appraised through the maintained flux ratios and the irreversible fouling factors of unmodified and modified membranes during 10 h-filtration of protein bovine serum albumin (BSA) in an aqueous solution, in which, before filtration of BSA, all membranes were immersed in E. coli bacteria solution for 4 days. The results of the experiments corroborated the hydrophilicity and more anti-microbial property of the membrane surfaces after being incorporated into AgNPs. The water contact angle decreased from around 49 for the unmodified membrane to 36 and 23 for the AgNPmodified membranes without/with PEG, while no colonies appeared in the medium containing the AgNP-modified membranes. The separation property of modified membranes was improved, with both membrane flux and antifouling properties, along with the substantial surge of the anti-biofouling property. After 10 h of BSA filtration, the fluxes of the modified membranes were maintained at 68% and 78% for AgNP-modified membranes without and with PEG, respectively. Conversely, this value was only 46% for the unmodified one.

Antibacterial and Antifouling Properties of Ag‐ and Cu‐Decorated Thin Film Composite Polyamide Reverse Osmosis Membranes

“…[16] AgNPs are well-known to be one of the most powerful antibacterial compounds because they can supply prolonged Ag + ions to prevent bacterial and fungal adhesion. [12,17,18] On the other hand, CuNPs are a promising candidate for membrane modification because they can release prolonged Cu + , and Cu 2 + ions with antibacterial properties. [19][20][21] The presence of nanoparticles minimizes the adhesion of the foulants and prevents the formation of a biofilm layer on the membrane surface and thus, reducing membrane fouling, especially the membrane biofouling phenomenon.…”

“…[25] Although the antibacterial and antifouling properties of the modified RO membranes were enhanced in the abovementioned studies, the permeability of the modified RO membranes was reduced which lowers the potential of the practical applications of these studies, unfortunately. [12,17,[18][19][20][21][22][23][24][25] This study is aimed at finding suitable Ag and Cu coating conditions that enhance the antibacterial and antifouling properties yet maintaining the permeability. We reckon that it can be achieved by appropriately reducing the concentration of Ag and Cu during the coating process.…”