The first part of this paper focuses on the chemical and thermal properties of pdMMA films, which are evaluated as a function of T substrate . Thermogravimetric analysis reveals a decreased low molecular weight fraction and enhanced cross-link density with increasing T substrate. In accordance, an enhanced glass transition is observed with differential scanning calorimetry. In a second part, a new Arrhenius-type empirical model is presented for the specific plasma deposition rate k 0 , i.e., k 0 ðY f ; TÞ ¼ A app ðY f Þ Á expðÀE app =ðR Á TÞÞ, with input plasma power and precursor feed rate (by means of the Yasuda factor, Y f ) and T of the substrate as variables of the plasma deposition process. A simplified plasma deposition mechanism is suggested based on adsorption, desorption, and surface plasma polymerization of activated species, justifying the experimental findings and empirical model.