We predict the existence of medium spin PDR and find experimental evidence in 80Ge using β-decay of 80Ga. This nucleus was produced in the photo-fission of 238U. A hybrid γ-ray spectrometer was developed using a plastic detector for β-tagging, HPGe detectors for low-energy γ rays detection and phoswich detectors of PARIS for high-energy γ rays. The low-high energy coincidence spectrum shows two peaks at 7181(53) and 7337(53) keV in the β-decay of the 80mGa isomeric state only, in coincidence with the 21+ → 0+ transition of 80Ge. Combined with decay information, electric dipole character (E1) were assigned to these γ rays which de-excite 7.84 MeV and 7.996 MeV states. Based on this fact and the comparison with theoretical calculations, we conclude that these enhanced E1 transitions are driven by neutron-skin oscillation of 80Ge. The oscillation is triggered by a conversion of a deeply-bound neutron from the Z=N=28 proton-neutron saturated core into a proton in the Fermi surface. These results provide an evidence for a PDR state with spin different from 1− and built on a low-energy excited state. Consequently, it extends the PDR’s boundary along spin dimension for the first time and provides experimental data for testing the validity of the Brink-Axel hypothesis in the PDR region.