Characterization of nanoparticle transport through quartz and dolomite gravels by magnetic resonance imaging

Abstract

Magnetic resonance imaging (MRI) has tremendous potential for revealing transport processes in engineered and geologic systems. Here, we utilize MRI to image nanoparticle (NP) transport through a saturated coarse-grained system. Commercially available paramagnetically tagged NPs are used; the paramagnetic tag making the NP visible to MRI. NP transport was imaged as NPs migrated through packed columns of quartz and dolomite gravel. Changes in T2-weighted image intensity were calibrated to provide fully quantitative maps of NP concentration at regular time intervals (T 2 being the spin-spin relaxation time of 1 H nuclei). Transport of nanoparticles was significantly retarded in dolomite compared to quartz due to electrostatic attraction between nanoparticle and dolomite surfaces. NP concentration profiles were evaluated with the CXTFIT computer package to estimate nanoparticle transport parameters at multiple points along the length of the column. This provided temporally resolved parameters that standard breakthrough curve analysis cannot provide. Particle-surface interaction energy profiles were described through Derjaguin-LandauVerwey-Overbeek (DLVO) theory. While dispersion coefficients and fast deposition rate constant (k fast ) were found to increase with distance, deposition rate constant (k) and collision efficiency (a) were found to decrease with distance. These length-dependant variations have significant scaling-up implications for transport models used to predict NP transport in natural and engineered coarsegrained systems, such as sustainable urban drainage systems and river beds.

Magnetic susceptibility monitoring and modelling (MSMM): A non-invasive method for acquiring and modelling exceptionally large datasets from column experiments with manufactured nanoparticles

“…Several non-invasive or minimally invasive methods exist including fluorescence imaging [6], scanning optical fibre fluorescence profilers [7], and positron emission projection imaging [8]. Magnetic resonance imaging has the potential to allow the high-resolution, three-dimensional investigation of transport through columns [9], although its use is restricted to media with low concentrations of ferromagnetic substances. None of the above are without disadvantages: a critical review of non-invasive monitoring techniques is given by Werth et al [10].…”