Four types of organic template were used to induce the nanowire microstructure of a sol-gel-deposited ZnO:Al:Mo films. Dip coating in one constant positive and one reverse direction was used to control the array of the ZnO:Al:Mo nanowires thus formed. Long and parallel arrayed nanowires were observed for the films deposited with the templates and showed obvious blueshifts and enhanced UV-visible transmittance. Polyethylene glycol-1000 and -2000 have a better effect than polyethylene glycol-4000 and polylevulinic pyrrolidone-k30. The films showed strong ultraviolet, violet, and bluish violet emissions. The templates also led to thicker films and more native defects, thereby enhancing photoluminescence to different degrees.
INTRODUCTIONZinc oxide (ZnO) semiconductor materials have many attractive properties, including high visible transparency, a high piezoelectric constant [1], and high operation temperature. These make ZnO materials highly suitable for applications in field effect devices, sensors, solar cells, and piezoelectric devices [2,3].Al, In, and Ga dopants, especially Al dopant, have been verified to be effective in improvement of properties [4-6]. Recently, Sn and Mo dopants have also been reported to be effective in widening the band gap of ZnO [5,7]. Moreover, it has been reported that the (Al, Sc) co-doping can lead to better electric conductivity and light transmittance of the ZnO film than Al doping and Sc doping [8]. Our previous studies revealed that an appropriate amount of W or Si co-doping can also widen the band gap and increase transmittance of ZnO:Al nanocrystalline [9, 10]. Furthermore, it is well-known that one-dimensional nanostructure and its reasonable array can induce special behavior for the materials and enhances certain electrical, optical, and mechanical properties of the materials. In this aspect, c-oriented ZnO films parallel to the substrate plane [11,12] or randomly arrayed on the substrate have shown wider band gap and stronger transmittance than randomly oriented films [13,14]. To induce onedimensional nanostructure, some long-chain organic molecules are generally used as template.We present the template effects on the morphology, band gap, transmittance, and photoluminescence of sol-gel-deposited ZnO:Al:Mo films in this article.