Characterization of groundnut shell biochar produced with different stainless steel combustion compartment volumes

Abstract

Biochar, a solid material derived from a thermochemical process, has received significant attention due to its usefulness in various sectors. Previous studies have been conducted to improve the properties and quality of this material by altering the thermochemical processes, treating the feedstock, hybridizing the feedstock, and so forth, but little has been done on the effect of varying the reactor's configuration. This research aims to study the effect of varying the stainless‐steel‐based combustion compartment volume of a biomass‐fueled top‐lit updraft gasifier on the groundnut shell biochar. The biochar yields for reactors ranged from 34.9% to 51.2%. The sample produced in the smallest combustion compartment volume showed the highest carbon content, according to energy dispersive X‐ray spectroscopy (EDX) analysis. Potassium, another major element, decreased as the combustion compartment was reduced. Scanning electron microscopy (SEM) analysis revealed that the biochar samples produced had an irregular shape and rough surfaces, and reducing the combustion compartment volume resulted in larger particles on the surface. Fourier transform infrared (FTIR) spectroscopy analysis showed similarities and differences in peaks observed for all the samples. The biochar samples produced can find applications in wastewater treatment, energy conversion and storage, and soil amendment, and the findings contribute to the design and optimization of biomass‐based gasifiers.