Recently, the polymer nanofiber web is in high demand as a strong barrier against
harmful particles due to its high capture efficiency and strong droplet-blocking
ability. As an advanced spinning technique, the centrifugal multispinning system was
designed by sectioning a rotating disk into triple subdisks, showing mass producibility
of polymer nanofibers with cospinning ability. Using the system, gram-scale production
of polystyrene (PS), poly(methyl methacrylate), and polyvinylpyrrolidone (PVP) was
demonstrated, showing a possibility for versatile use of the system. Moreover, a high
production rate of ∼25 g/h for PS nanofibers was achieved, which is
∼300× higher than that of the usual electrospinning process. Utilizing the
cospinning ability, we controlled the contact angle and electrostatic charge of the
multicomponent nanofiber web by adjusting the relative amounts of PS and PVP fibers,
showing a potential for functional textile application. With the fabricated PS
nanofiber-based filters, we achieved high capture efficiency up to ∼97% with
outstanding droplet-blocking ability.