Characterization of Dyestuffs and Metals from Selected 16–17th-Century Ottoman Silk Brocades by RP-HPLC-DAD and FESEM-EDX

Karadağ, Recep; Torgan, Emine; Taşköprü, T.; Yildiz, Yusuf

doi:10.1080/10826076.2014.922476

Cited by 18 publications

(13 citation statements)

References 32 publications

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“…The HPLC analysis of the pigments was performed as described in earlier reports (36)(37)(38)(39). Acetonitrilewater and water-trifuluoroacetic acid were used as the mobile phase.…”

Section: Hplcmentioning

confidence: 99%

Characterization of the Alphabet Reform Painting

Cakmak

Karadağ

Kayaman‐Apohan

et al. 2021

Journal of the Turkish Chemical Society Section A: Chemistry

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The Alphabet Reform painting which shows Ataturk teaching the new alphabet is important for the history of the Republic of Turkey. This painting was made by Nazmi Ziya GÜRAN in 1933. The painting is now maintained by the Ministry of Interior. In this work, the Alphabet Reform painting was analyzed for characterization and restoration purposes. The fabric of the canvas, pigments (organic-inorganic) and the binder of paint were characterized by Fourier Transform infrared spectroscopy-attenuated total reflectance (ATR-FTIR), scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDX) and highperformance liquid chromatography-coupled with diode array detection (HPLC-DAD) analysis methods. The CIEL*a*b* color parameters of the paint were determined by color measurement spectrophotometer. According to the results, the canvas was found to be of fibers of vegetable origin and the binders were determined to be linseed oil and dammar varnish. Red alizarin (madder lake organic pigment) and dark blue ultramarine pigments were detected as the organic pigments while CdS (yellow), Pb red (flesh color), PbCO3 (white), ZnO (white), BaSO4 (white), FeO (brown) and Cr2O3 (green color) were detected as the inorganic ones.

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“…The HPLC analysis of the pigments was performed as described in earlier reports (36)(37)(38)(39). Acetonitrilewater and water-trifuluoroacetic acid were used as the mobile phase.…”

Section: Hplcmentioning

confidence: 99%

Characterization of the Alphabet Reform Painting

Cakmak

Karadağ

Kayaman‐Apohan

et al. 2021

Journal of the Turkish Chemical Society Section A: Chemistry

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“…Partial hydrolysis of pseudopurpurin and munjistin was reported by Wouters [13] during dye extraction from textile fibres in the original HCl-extraction procedure. The HCl-based extraction procedure is still a widely accepted approach [41,54,[125][126][127][128][129][130][131][132] with modifications to hydrolysis conditions [116,133,134] and use of alternative solvents solvents (MeOH [116,135], DMF [136], MeOH/DMF [137,138], MeOH/formic acid [139], DMSO [50,140,141]…”

Section: Sampling and Dye Extraction Protocolsmentioning

confidence: 99%

“…Reversed-phase high-performance liquid chromatography (RP-HPLC) is the most common mode for separation of historical anthraquinone dyes [15]. The most employed experimental procedure for the RP-HPLC analysis of anthraquinone dyes generally involves a C18 [13,42,131,144,146,150,156], C8 [143] or C4 [10,148] based non-polar stationary phase and mobile phases consisting of pure water (aqueous) and acetonitrile or MeOH (organic) eluents [15], with formic acid [6,148,157,158], trifluoroacetic acid [131,136,146,150,159], phosphoric acid [137,160] or methanesulphonic acid [161] added as mobile phase modifiers.…”

Section: Mmentioning

confidence: 99%

Analytical methods for determination of anthraquinone dyes in historical textiles: A review

Shahid

Wertz

Degano

et al. 2019

Analytica Chimica Acta

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Historical and archaeological textiles are among the most crucial and vulnerable records of our social and cultural history. Analysis of organic colorants found in these materials is unquestionably one of the most powerful tools to understand historical developments, cultural exchanges, and progress in science and technology. Natural anthraquinones represent the most commonly used natural colorants for textile dyeing until the late 19 th century. The identification of anthraquinones in cultural heritage objects is a challenging task due to the small size of historical samples, diversity of potential dye sources, variable extraction procedures and dyeing methods, complex chemical constitution, structurally analogous chromophores, and possible presence of degradation products and contaminants. Developments in dye analysis of historical interest have originated and expanded along with the general advances in analytical science. In the last few decades, a close cooperation between science and cultural heritage disciplines contributed enormously to this field. The topic of historical dyes and their analysis in textiles, artworks, archaeological objects and cultural heritage materials has been reviewed several times in the last fifteen years. However, no review has been published to-date exclusively on the analysis of anthraquinone colorants in historical and archaeological textiles. Overall, liquid chromatography (LC)-based techniques have been the most widely used method for anthraquinone dye analysis. Owing to increasing demand of minimally invasive/non-invasive techniques, recent developments of novel techniques have resulted in the availability of many alternative/complementary methods to LC-based analysis. This review begins with a short overview of sources, chemistry and importance of natural anthraquinone dyes found in historical textiles before turning to a detailed discussion on developments involving established and emerging analytical techniques of anthraquinone dye analysis for textile cultural heritage materials. To illustrate the state-of-the-art, representative examples of analytical techniques highlighting their advantages, limitations and applicability are also presented.

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“…Reference Historical textiles [17], [30], [94], [130][131][132][133][134][135][136][137] Textile dyeing [5], [7][8][9], [14], [26], [42], [87], [89], [106], [111], [124], [125], [138][139][140][141]] Natural lake pigment [41], [90], [95], [97], [121], [142][143][144][145] Medieval manuscript, easel painting [18], [146] Mural painting, icons […”

Section: Application Areamentioning

confidence: 99%

Doğal Boya Kaynağı – Flavonoidler Üzerine Derleme

Deveoğlu

Karadağ

2019

International Journal of Advances in Engineering and Pure Sciences

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In this study, the short information was given about flavonoids giving yellow colour to plants present in nature. In addition to these, flavones, flavonols, flavanones and isoflavonoids as subgroups were also reviewed. Among these subgroups, flavones and flavonols are one of the most important classes of phenolic compounds. The information about the most important dye plants including flavonoids was also given in this study. The investigated plants are weld (Reseda luteola L.), onion (Allium cepa L.), young fustic (Cotinus coggygria SCOP), Anatolian buckthorn (Rhamnus petiolaris Boiss), dyer's greenwood (Genista tinctoria L.) and Spanish broom (Spartium junceum L.). The most important yellow dyestuff and the oldest European dye among these dye sources is known as the luteolin dye. The dye plants were used for yellow color dyeing in ancient and historical textile. Nowadays, flavonoids are reused for sustainable, non-toxic, green textile and environment friendly textile dyeing. In the same time, flavonoids have been used for natural lake organic pigment, cosmetic, pharmaceuitical industries. In recent years, it has been suggested to use flavones in textile dyeing, cosmetic, pharmaceutical, etc. industries by the World Health Organization (WHO). Therefore, we have aimed to contribute to similar studies theoretical and experimental in natural dyeing studies.Keywords: Flavonoid, natural dye, dye plant. ÖzBu çalışmada, doğadaki mevcut bitkilere sarı renk veren flavonoidler hakkında kısa bilgi verilmiş olup, ek olarak da, bu bileşiklerin alt grupları olan flavonlar, flavonollar, flavanonlar ve isoflavonoidler hakkında genel bilgiler sunulmuştur. Bu alt gruplar arasında flavonlar ve flavonollar fenolik bileşiklerin en önemli sınıflarından birisidirler. Flavonoidleri içeren en önemli boya bitkileri hakkında bilgiler de bu çalışmada verilmiştir. İncelenmiş bitkiler muhabbet çiçeği (Reseda luteola L.), soğan (Allium cepa L.), boyacı sumağı (Cotinus coggygria SCOP), cehri (Rhamnus petiolaris Boiss), boyacı katırtırnağı (Genista tinctoria L.) ve katırtırnağı (Spartium junceum L.)'dır. Bu boya kaynakları arasında en önemli sarı boyarmaddesi luteolin'dir. Anadolu ve Avrupa'ya özgü boyarmaddenin en önemlilerinden birisi olarak bilinir. Bir çok boya bitkisi antik ve tarihi tekstillerde sarı renk boyamacılığı için kullanılmıştır. Günümüzde, flavonoidler sürdürülebilir, toksik olmayan, eko tekstil ve çevre dostu tekstil boyamacılığı için yeniden kullanılmaya başlanmıştır. Aynı zamanda, flavonoidlerin doğal lak organik pigment, kozmetik ve ilaç endüstrisi için kullanımı yeniden artmıştır. Son yıllarda, Dünya Sağlık Örgütü (WHO) tarafından tekstil boyamacılığında, kozmetik ve ilaç endüstrileri ve benzeri alanlarda flavonların kullanımı önerilmiştir. Bu nedenle, bu çalışmada doğal boyarmaddelerin teorik ve deneysel benzer çalışmalara katkı sağlaması amaçlanmıştır.Anahtar Kelimeler: Flavonoid, doğal boya, boya bitkisi.

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Characterization of Dyestuffs and Metals from Selected 16–17th-Century Ottoman Silk Brocades by RP-HPLC-DAD and FESEM-EDX

Cited by 18 publications

References 32 publications

Characterization of the Alphabet Reform Painting

Characterization of the Alphabet Reform Painting

Analytical methods for determination of anthraquinone dyes in historical textiles: A review

Doğal Boya Kaynağı – Flavonoidler Üzerine Derleme

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