“…For example, tribological phenomena such as friction and wear are directly linked to the nature of the real area of contact between the surfaces which is, in turn, dependent upon the distributions, sizes and shapes of the asperities [1][2][3]. On the other, optical devices such as I.R windows and lenses need antireflection diamond coatings whose characteristics are determined by the uniformity and the smoothness [4]. Independently of diamond applications, the realisation of highly oriented diamond films by means of plasma assisted CVD techniques needs a cathodic polarisation of the substrate [5][6][7][8].…”