“…The presence of nitrogen in the XPS survey spectrum can be probably appointed to the interaction of AA, or the products of its plasma-polymerization, with vibrationally excited N 2 molecules, resulting from the mixing of the plasma plume with the surrounding air, [43] as proposed by Bhatt et al [54] for the case of plasmapolymerization of diethylene glycol dimethyl ether; indeed, they observed by means of optical emission spectroscopy the formation of OH, CH, N 2 , and CN excited species when the monomer was introduced into the Ar plasma jet. The curve fitting of the high-resolution C 1s peak, shown in Figure 7, provides useful information on the retention of carboxyl groups in the chemical structure of the pPAA matrix of the nanocomposite coating.…”