Characterization and physical properties of hydrated zinc borates synthesized from sodium borates

Abstract

In this study, Zn

An accelerated and effective synthesis of zinc borate from zinc sulfate using sonochemistry

“…According to the XRD results, the as-synthesized compound was defined as "zinc oxide borate hydrate (Zn 3 B 6 O 12 •3.5H 2 O)" with the pdf No. "00-035-0433" and was identical to that previously reported in the literature (Bardakci et al, 2013;Ersan et al, 2016;Kipcak et al, 2014Kipcak et al, , 2015Kipcak et al, , 2016Vardar et al, 2017). The as-synthesized zinc borate compound's XRD results are given in Figure 1.…”

“…Zheng et al (2009) produced zinc 4ZnO•B 2 O 3 •H 2 O that is form of zinc borate using with Zn(NO 3 ) 2 •6H 2 O. Acarali et al (2013) examined different modification agents' effects used to procure hydrophobic zinc borate product at between 50-120°C over 1-5 h. Kipcak et al (2016) obtained zinc borate from boric acid and zinc oxide 1-5 h and at 95°C. Sonochemical systems create multi-bubble environments in which chemical reactions occur with the strong and rapid connection of the reactants.…”

A Novel Synthesis of Zinc Borates from a Zinc Oxide Precursor via Ultrasonic Irradiation

“…The 28 Therefore, it is seen that the ultrasonic irradiation method used in this study decreased the reaction times slightly.…”

“…The observed characteristic peaks agree with the literature. [27][28] The effect of reaction temperature and reaction time on the formation of zinc borate is shown in Fig. 2b, produced with Statistica 8.0 software (StatSoft Inc., OK, USA).…”

“…The bands between 1411 cm -1 and 1252 cm -1 are associated with asymmetric stretching of the three-coordinate boron to oxygen bands [ν as (B (3) 28 The Raman spectra of zinc borate compounds produced from selected reactions are shown in Fig. 3b.…”