A novel motionless mixer named Ramond supermixer (RSM) was used to disperse nanoparticle suspensions
under the various process conditions. Commercially available nanoparticles, fumed silica (SiO2) of primary
particle diameter (d
0) ranging from 7 to 30 nm, zirconia (ZrO2) of d
0 = 12 nm, and titanium oxide (TiO2) of
d
0 = 21 nm, were dispersed either in an ion-exchanged water or in aqueous ethylene glycol solutions. The
smaller the d
0, the harder it is to disperse the aggregates. Zeta potential was largely dependent on d
0 and
became independent of process variables and, hence, of aggregate diameter. By evaluation of energy barrier
values, the aggregation during disruption was found to be negligible. Aggregate disruption was predominant
at the viscous subrange. By balancing mechanical energy with turbulent disruptive energy, a mechanistic
model was developed for aggregate disruption. The analysis of fractal dimension showed that nanoaggregates
are made up by orthokinetic cluster−cluster collision. Fractal dimensions are invariant throughout the disruption
process. The rheological measurements further confirmed the evaluated fractal dimensionality.