Characteristics of Ag Doped ZnO Thin Films Prepared by Sputtering Method

Abstract

This paper presents results of preparation of Ag doped ZnO bulk sample by solid state reaction and Ag doped ZnO thin films by sputtering method. Effect of doping concentration (1, 2 and 4%) on the properties of the thin films was investigated. Various methods were utilized to investigate characteristics of the samples: X-ray diffraction, Raman scattering spectroscopy, photoluminescence, energy dispersive X-Ray spectroscopy, scanning electron microscopy, atomic force microscope, absorption spectroscopy and Hall measurement. The results show that Ag diffused into ZnO crystal lattice after heat treatment at 1200oC. As-prepared thin film samples exhibit low resistivity in the order of 10-3Ω.cm. The film doped with 2% Ag shows the lowest resistivity of 1.8´10-3Ω.cm which is potential for making transparent electrodes in optoelectronics.

Elaboration and characterization of pure ZnO, Ag:ZnO and Ag-Fe:ZnO thin films: Effect of Ag and Ag-Fe doping on ZnO physical properties

“…Optoelectric properties of ZnO depend on deposition technique, annealing and the element nature used. Depending on where the Silver (Ag) is positioned within ZnO crystal lattice, Ag-doped ZnO (ZnO:Ag) can exhibit either n-or p-type conduction [15]. The type of ZnO conduction depends on the rivalry between Ag + Zn and Ag i since these defects coexist peacefully in the ZnO lattice.…”