The present work investigated the variation of internal structure, molecular orientation, crystallinity and mechanical characteristics of polypropylene(PP) after rolling process. The materials plate became narrow when rolled from entrance to exit, and the internal crystalline gradually deformed and at last destroyed. Plastic deformation was discovered along the rolling direction. In this direction, the crystallinity and vickers hardness were decreased, and molecular orientation was increased. Moreover, molecular orientation had a sharp increase at the second half part of rolling sample. The tensile stress of rolled samples increased by 80% parallel to rolling direction and decreased by 22% perpendicular to rolling direction.