Characterisation of organoboron ligands by electrospray mass spectrometry using anhydrous solvent application

Libot, Francine; Virelizier, H.; Froelich, Olivier; Bonin, Martine; Quirion, J.‐C.; Husson, Henri‐Philippe

doi:10.1002/oms.1210291212

Cited by 2 publications

(1 citation statement)

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“…62,63 Other air-sensitive organoboron ligands such as diazaborolidine complexes have been successfully analyzed by ESI-MS in anhydrous THF. 64 Transition metals play a seminal role in selectively breaking or activating C-H and C-C bonds of hydrocarbons. This process, known as 'oxidative addition,' is of paramount importance in catalytic and synthetic chemistry.…”

Section: Organometallic and Inorganic Chemistrymentioning

confidence: 99%

Unravelling seemingly complex chemistry of reactions using electrospray ionization mass spectrometry

Bakhtiar

Hop

1999

J. Phys. Org. Chem.

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Since its discovery, electrospray ionization mass spectrometry (ESI-MS) has provided valuable information on structurally specific biomolecular interactions, including DNA-drug, enzyme-inhibitor, DNAprotein and protein-protein interactions. In addition, this technique has emerged as a powerful tool in probing the structural modification of large molecules. However, ESI-MS has been underutilized in analysis and mechanistic studies involving small molecules. Here, a brief overview is presented to familiarize non-specialists with ESI-MS applications in analysis and mechanistic studies of small molecules. For more advanced applications (e.g. biopolymers) or detailed analytical descriptions of the ionization processes and the equipment, readers are referred to a number of excellent reviews and books.

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Section: Organometallic and Inorganic Chemistrymentioning

confidence: 99%