2007
DOI: 10.3184/030823407x227499
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Characterisation of a Mixed N-heterocycle, 2-(N-methylimidazole-2′-yl-thiomethyl)benzimidazole, and its complexes with nickel(II) and copper(II)

Abstract: 2-(N-methylimidazole-2′-yl-thiomethyl)benzimidazole (L) has been synthesised and the complexes [ML2 (ClO4)2]·2H2O (M = Ni or Cu) and [MLX2] nH2O (M = Cu, X = Cl or Br, n = 0; M = Ni, X = Cl, n = 3; M = Ni, X = Br, n = 0) prepared and characterised. Proposed geometries for the complexes are: octahedral geometry for perchlorate complexes; tetrahedral geometry for chloro-and bromo-complexes; dimeric square pyramidal for the chloro-complex of copper(II).

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Cited by 4 publications
(2 citation statements)
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“…Compounds were directly taken to next step without purification. NMR and LCMS data complies with literature data (Satyanarayana and Nagasundara, 2007).…”
Section: Synthesis Of the Compounds (3a-c)supporting
confidence: 79%
“…Compounds were directly taken to next step without purification. NMR and LCMS data complies with literature data (Satyanarayana and Nagasundara, 2007).…”
Section: Synthesis Of the Compounds (3a-c)supporting
confidence: 79%
“…With this in mind, there have been investigations on the reactions of transition metal ions with a wide range of N-heterocycles. 11,12 We have synthesised the Schiff base, 2-salicylidine-4-aminophenyl benzimidazole (SAPbzlH; LH) and we report here its reactions with salts of Zn, Cd and Hg.…”
mentioning
confidence: 99%