The
present study reports an enhancement of the power factor of
Bi
2
Te
3
nanorods NRs) by helium (He
+
) ion irradiation. High-resolution transmission electron microscopy
studies revealed the formation of amorphous layers on the surface
of the NRs at the high ion fluence. This amorphous nature is due to
the accumulation of migrating point defect clusters at the surface
of the NRs. Raman scattering experiments provide further insight to
the observed structural modifications. At higher ion fluence, impurity-dominated
scattering processes significantly enhance the value of the Seebeck
coefficient of Bi
2
Te
3
NRs. The He
+
ion irradiation up to the ion fluence of 1 × 10
16
ions/cm
2
improves the thermoelectric transport properties
with the highest power factor, 8.2 μW/m K
2
, at 390
K. Further investigations may result in the possibility of fabricating
the Bi
2
Te
3
NRs as thermoelectric generators
with a high power factor for space applications.