Indicators synthesizing the state of the structural quality and the function of the porous system are useful for assessing soil production capacity as well as the way it may serve natural ecosystems. This research aimed (i) to determine indicators of the state and function of the porous system, (ii) to use them to derive a global index to characterize the soil physical quality, and iii) to establish a reference pore-size distribution curve for Mollisols from the province of Santa Fe (Argentina). Sixty water retention curves (WRC) of A and B horizons of Mollisols, with clay varying between 119 and 538 g kg . Both the high silt content and low organic matter content confer on the soil characteristics with low stability, excess of small pores and low porosity of the macropore domain. Consequently, the capacity to quickly drain the water excess and allow root proliferation was not optimal, possibly due to the high silt or clay content and the low sand content, characteristic of the soil matrix of these Mollisols.