The relation between the electron-electron correlations and magnetic-field-induced angular momentum transitions in the barrier D − centre is investigated based on a variational method. The Chandrasekhar-type variational wavefunctions for the barrier D − states are constructed based on the exact solutions in the strong-magnetic-field limit. The energies of the barrier D − states, the binding energies, the electron densities, the angular correlations, and the average distances between the two electrons are obtained as functions of the applied magnetic field strength γ and the distance ζ between the positive ion and the plane where the two electrons reside. When the transitions of the barrier D − ground state occur for finite ζ with increasing γ , the strong correlations appear in the electron densities, the angular correlations, and the average distances between the two electrons. As a consequence of detailed considerations of the relation between the angular correlations and the strength of binding, we find that the magnetic-fieldinduced angular-momentum transitions occur as a result of the strong correlations in the barrier D − states.