Chance, Character and Change

Mattausch, John

doi:10.4324/9781315081588

Cited by 2 publications

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“…The same "sliding" of slabs to get from the 3R structure to the 1-slab hydrates has been observed in the hydration reactions. It is presumed that the change from the 3R to the IT struc ture, which involves the change in coordination of the Cs from trigonal antiprismatic to trigonal prismatic, involves a small energy change that reflects the fact that the large cesium atom is equally well-coordinated in the trigonal prismatic hole.DeintercalatlonThe oxidation of 2H-and 3R-M^YC10 to YClO was achieved with I" to reaction(3). The solvent in all these reactions was dried(3) M^YCIO + 1/2I"(solution) • YClO + oM^I, where M^=Li,K a typical reaction 50-100 mg of sample was reacted with an excess of Ig in acetonltrlle for 1-2 days at room temperature.…”

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Intercalation of interstitial derivatives of yttrium monochloride

Ford

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confidence: 99%