Challenges of thermal stability of high-energy layered oxide cathode materials for lithium-ion batteries: A review

Deng, Zicen; Liu, Yan; Wang, Li; Fu, Ni; Li, Yuan; Luo, Yixin; Wang, Jinkun; Xiao, Xiang; Wang, Xianyou; Yang, Xiukang; He, Xiangming; Zhang, Hao

doi:10.1016/j.mattod.2023.07.024

Cited by 27 publications

(6 citation statements)

References 207 publications

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“…Meanwhile, the Jahn-Teller (J-T) effect of Ni 3+ ions accelerates Ni ion dissolution into the electrolyte, which leads to cathode electrode degradation at the surface, cationic mixing, and phase transition. 52,53 The amount of dissolved transition metal ions can be used as an indication of the role of CEI film in protecting the cathode electrode. 38 In this study, the synthetic LiF-rich robust CEI layer can significantly reduce the dissolution of transition metal ions, as demonstrated by ICP-MS (Figs.…”

Section: Resultsmentioning

confidence: 99%

Quenching-Induced Ultrathin LiF-Rich Interphases on LiNi_0.8Co_0.1Mn_0.1O₂ Cathode

Li,

Zhang,

Chen

et al. 2024

J. Electrochem. Soc.

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Nickel-rich layered oxides (NCM) are a promising contender material for the cathode electrode of high-energy lithium-ion batteries (LIBs) due to their large reversible capacity and high operating voltage. However, the poor surface/interfacial stability and the dissolution of transition metal ions hinder the commercial application of NCM. To create an artificial cathode electrolyte interphase (CEI) with LiF-rich inorganic phase on the NCM surface, a practical and efficient way of quenching the NCM powder from high temperature in 1,1,2,2-Tetrafluoroethyl 2,2,2-trifluoroethyl ether (HFE) was devised. With this artificial CEI film, the side reactions between NCM and electrolytes are inhibited, and the dissolution of TM ions is retarded. The quenched-NCM achieved fantastic cycling performance and suppressed voltage decay. Our research offers an efficient and worthy approach for improving the surface/interfacial stabilization of nickel-rich cathode materials for high-energy-density LIBs.

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Section: Resultsmentioning

confidence: 99%

Quenching-Induced Ultrathin LiF-Rich Interphases on LiNi_0.8Co_0.1Mn_0.1O₂ Cathode

Li,

Zhang,

Chen

et al. 2024

J. Electrochem. Soc.

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“…According to the C 1s fine XPS spectra of NM90 and NM90-1%AB materials, the integral area ratio of CO 3 2– in NM90-1%AB materials is smaller, confirming the reduction in Li 2 CO 3 on the surface. The lower harmful residual alkali on the surface of NM90-1%AB material can effectively reduce the release of CO 2 and O 2 during the cycles, thereby reducing the deterioration of electrochemical performance and catastrophic thermal runaway Figure d shows the fine XPS spectra of B 1s of NM90-1%AB material, with the characteristic peaks at binding energies of 191.7 and 192.7 eV corresponding to LiBO 2 and B 2 O 3 , respectively. , It is noteworthy that the fitting results indicate a very low content of B 2 O 3 .…”

Section: Resultsmentioning

confidence: 99%

“…11 During the cycling process, the residual alkalis will release CO 2 and O 2 , which can lead to potential safety issues such as deterioration of electrochemical performance, catastrophic thermal runaway, and even explosion. 12 It should also be noted that the highly active Ni 4+ in the highly charged state will lead to decomposition of the electrolyte. The HF generated by the side reaction of H 2 O and LiPF 6 will corrode the surface/interface of the materials.…”

Section: ■ Introductionmentioning

confidence: 99%

B/Al Codoped/Coated Ultra-High Nickel Cobalt-Free Material with Excellent High Voltage/Rate Cycle Stability

Zhang,

Huang,

Tang

et al. 2024

ACS Sustainable Chem. Eng.

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Ultrahigh nickel cobalt-free cathode materials have high energy density and are very promising materials for application in lithium-ion batteries. However, they face severe challenges of overall degradation in the interface/lattice structure stability during charge and discharge, resulting in poor safety and a short cycle life. In this paper, the B/Al codoping/coating is applied to LiNi 0.9 Mn 0.1 O 2 (NM90). The LiAlO 2 /LiBO 2 coating formed in situ by B/Al and surface residual alkali helps to reduce O 2 evolution and restrain side reactions on surface. The B/Al codoping resulting from hightemperature thermal diffusion significantly expands the layer spacing, thus improving the Li + diffusion rate. After 300 cycles, the optimized NM90-1% AB material achieves 86.5% capacity retention (1 C, 2.7− 4.3 V, 25 °C) compared to 68.5% for the pristine NM90 material. Furthermore, its capacity retention can reach 84.7% after 300 cycles at 4.4 V and 5 C, which is much higher than the 58.9% of NM90 material. Even at 10 C, the specific discharge capacity of the NM90-1% AB material can still reach 155.1 mA h/g, but the NM90 material only has 142.8 mA h/g. It is obvious that the B/Al codoped/coated strategy can enhance the interface/lattice structural stability of NM90 material.

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“…Since layered oxide cathodes exhibit the advantages of high energy density in the case of SIBs and LIBs, they are always considered promising cathodes for constructing high-performance potassium ion full cells. 40–44 Many detailed review publications have been made on layered PIB cathodes and carbon-based anodes, but many new research publications bring many innovative perspectives. In this review, we first summarize the developed promising layered oxide cathodes and their potassium intercalation/deintercalation mechanisms, followed by a special emphasis on full-cell performance.…”

Section: Introductionmentioning

confidence: 99%

Strategies for developing layered oxide cathodes, carbon-based anodes, and electrolytes for potassium ion batteries

Lin,

Luo,

Cong

et al. 2024

Mater. Horiz.

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Challenges of thermal stability of high-energy layered oxide cathode materials for lithium-ion batteries: A review

Cited by 27 publications

References 207 publications

Quenching-Induced Ultrathin LiF-Rich Interphases on LiNi_0.8Co_0.1Mn_0.1O₂ Cathode

Quenching-Induced Ultrathin LiF-Rich Interphases on LiNi_0.8Co_0.1Mn_0.1O₂ Cathode

B/Al Codoped/Coated Ultra-High Nickel Cobalt-Free Material with Excellent High Voltage/Rate Cycle Stability

Strategies for developing layered oxide cathodes, carbon-based anodes, and electrolytes for potassium ion batteries

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Challenges of thermal stability of high-energy layered oxide cathode materials for lithium-ion batteries: A review

Cited by 27 publications

References 207 publications

Quenching-Induced Ultrathin LiF-Rich Interphases on LiNi0.8Co0.1Mn0.1O2 Cathode

Quenching-Induced Ultrathin LiF-Rich Interphases on LiNi0.8Co0.1Mn0.1O2 Cathode

B/Al Codoped/Coated Ultra-High Nickel Cobalt-Free Material with Excellent High Voltage/Rate Cycle Stability

Strategies for developing layered oxide cathodes, carbon-based anodes, and electrolytes for potassium ion batteries

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Product

Resources

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Quenching-Induced Ultrathin LiF-Rich Interphases on LiNi_0.8Co_0.1Mn_0.1O₂ Cathode

Quenching-Induced Ultrathin LiF-Rich Interphases on LiNi_0.8Co_0.1Mn_0.1O₂ Cathode