Challenges, mitigation strategies and perspectives in development of Li metal anode

Abstract

Lithium (Li) metal anode has been considered as the most promising anode for rechargeable batteries with high energy density owing to its extraordinarily high theoretical specific capacity (3860 mAh g −1) and the lowest negative electrochemical potential (-3.040 V vs. the standard hydrogen electrode). However, the practical applications of the Li metal anode are hampered by several obstacles, such as irrepressible dendritic Li growth and limited Coulombic efficiency (CE) during Li plating/stripping. To improve the application scope of Li metal batteries, it is imperative to develop advanced strategies to figure out these issues. In this Review, we first clarify the fundamental factors that affect the dendrite growth and CE of the Li metal anode. Subsequently, based on the previous theoretical understanding and analysis, recently proposed strategies to suppress dendrite growth and accommodating volume change have been reviewed. In addition, advanced characterization techniques for Li metal anode are included. Finally, a general conclusion and a perspective for the coming development of Li metal anode in practical applications are provided.

Structural and electronic properties of fluorine-doped lithium oxide as a solid electrolyte interphase for lithium air batteries

“…Despite low electrode potential and high theoretical capacity, lithium metal anodes have several limitations that prevent their use in rechargeable batteries. The formation of lithium dendrites during cycling is one of the most significant challenges with lithium metal anodes [5][6][7]. Dendrite needle-like structures that grow on the surface of the lithium electrode can pierce the separator and cause short circuits, poor battery performance, and safety risks.…”