Chalcone oxime derivatives as new inhibitors corrosion of carbon steel in 1 M HCl solution

Thoume, A.; Left, D. Benmessaoud; Elmakssoudi, Abdelhakim; Benhiba, F.; Zarrouk, A.; Benzbiria, N.; Warad, Ismail; Dakir, Mohamed; Azzi, M.; Zertoubi, M.

doi:10.1016/j.molliq.2021.116398

Cited by 41 publications

(10 citation statements)

References 67 publications

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“…Synthesis of Chalcone Oxime (CO). CO was reconstituted according to our previous work 37 by adding 1 mmol of chalcone, 1.5 mmol of hydroxylamine hydrochloride, and 1 mmol of anhydrous sodium sulfate in a volume of 5 mL of ethanol. After 3 h (end of the reaction), the resultant mixture was filtered, and the solvent was removed.…”

Section: ■ Materials and Methodsmentioning

confidence: 99%

Performance Evaluation of New Chalcone Oxime Functionalized Graphene Oxide as a Corrosion Inhibitor for Carbon Steel in a Hydrochloric Acid Solution

et al. 2022

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This study aims to synthesize new chalcone oxime functionalized graphene oxide (CO-GO) and investigate the enhancement in corrosion protection. The morphology and structure of the synthesized CO-GO have been characterized by elemental analysis: Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermal gravimetric analysis (TGA), and scanning electron microscopy (SEM). Moreover, the effectiveness of corrosion inhibition was investigated by utilizing electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization (PDP). The results of the above analyses demonstrate that CO-GO has an outstanding corrosion inhibitor performance of up to 94% and acts as a mixed-type inhibitor with a primarily anodic action. The effect of temperature on a carbon steel surface indicates that the tested composites are chemisorbed. A few techniques were able to provide surface characterization such as scanning electron microscopy and ultraviolet (UV)−visible spectroscopy to confirm inhibitor adsorption on the carbon steel surface.

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Section: ■ Materials and Methodsmentioning

confidence: 99%

Performance Evaluation of New Chalcone Oxime Functionalized Graphene Oxide as a Corrosion Inhibitor for Carbon Steel in a Hydrochloric Acid Solution

et al. 2022

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“…Several authors reported that the observed behavior might be the consequence of the low chemical performance of inhibitory molecules as temperature rises, which leads in turn to their desorption from CS surface. 44 Further details on the adsorption ability of the investigated inhibitors were given through the evaluation of various activation parameters such as E a (activation energy), ΔH a * (activation enthalpy), and ΔS a * (activation entropy). These descriptors were assessed by examining the temperature influence as expressed by the Arrhenius law (eq 8) and transition state formula (eq 9) 45 = i k j j j y…”

Section: Effect Of Temperaturementioning

confidence: 99%

Adsorption and Inhibition Mechanisms of New Pyrazole Derivatives for Carbon Steel Corrosion in Hydrochloric Acid Solutions Based on Experimental, Computational, and Theoretical Calculations

Adlani,

Benzbiria,

Titi

et al. 2024

ACS Omega

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The study aims to synthesize two green pyrazole compounds, N-((1H-pyrazol-1yl)methyl)-4-nitroaniline (L4) and ethyl 5-methyl-1-(((4-nitrophenyl)amino)methyl)-1H-pyrazole-3-carboxylate (L6), and test their action as corrosion inhibitors for carbon steel (CS) in a 1 M HCl solution. Both chemical and electrochemical methods, namely, gravimetric measurements (WL), potentiodynamic polarization (PDP), and electrochemical impedance spectroscopy (EIS), were used to assess the efficiency of the investigated molecules. DFT calculations at B3LYP/6-31++G (d, p) and molecular dynamics simulation were used to carry out quantum chemical calculations in order to link their electronic characteristics with the findings of experiments. The organic products exhibited good anticorrosion ability, with maximum inhibition efficiencies (IE %) of 91.8 and 90.8% for 10 −3 M L6 and L4, respectively. In accordance with PDP outcomes, L6 and L4 inhibitors act as mixed-type inhibitors. Assessment of the temperature influence evinces that both L4 and L6 are chemisorbed on CS. The adsorption of L4 and L6 on CS appears to follow the Langmuir isotherm. Scanning electron microscopy and UV−visible disclose the constitution of a barrier layer, limiting the accessibility of corrosive species to the CS surface. Theoretical studies were performed to support the results derived from experimental techniques (WL, PDP, and EIS).

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“…However, CS is vulnerable to corrosion through industrial operations, for example, industrial cleaning, acid pickling, acidizing, etc. 3 − 5 The industrial cleaning performed by H 2 SO 4 is utilized more often than HCl and HNO 3 . It could be ascribed to its cheap price; it does not cause pitting corrosion and its stability at higher temperature.…”

Section: Introductionmentioning

confidence: 99%

“…Carbon steel (CS) is a widespread engineering and structural material in manufacturing applications , because of its outstanding mechanical property and low cost. However, CS is vulnerable to corrosion through industrial operations, for example, industrial cleaning, acid pickling, acidizing, etc. − The industrial cleaning performed by H 2 SO 4 is utilized more often than HCl and HNO 3 . It could be ascribed to its cheap price; it does not cause pitting corrosion and its stability at higher temperature.…”

Section: Introductionmentioning

confidence: 99%

Efficient Synthesis of 6,7-Dihydro-5H-cyclopenta[b]pyridine-3-carbonitrile Compounds and Their Applicability As Inhibitor Films for Steel Alloy Corrosion: Collective Computational and Practical Approaches

et al. 2022

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An effective method for designing new heterocyclic compounds of 6,7-dihydro-5H-cyclopenta[b]pyridine-3-carbonitrile derivatives (CAPDs) was presented through cyclocondensation reaction between 2,5-diarylidenecyclopentanone derivatives and propanedinitrile, and the cyclocondensation reaction succeeded using a sodium alkoxide solution (sodium ethoxide or sodium methoxide) as the reagent and the catalyst. The synthesized CAPD derivatives were employed as novel inhibitors for carbon steel (CS) corrosion in a molar H 2 SO 4 medium. The corrosion protection proficiency was investigated by electrochemical measurements (open circuit potential vs time ( E OCP vs t ), potentiodynamic polarization plots (PDP), and electrochemical impedance spectroscopy (EIS)) and surface morphology (scanning electron microscopy (SEM)) examinations. The results show that the CAPD derivatives exhibit mixed type inhibitors and a superior inhibition efficiency of 97.7% in the presence of 1.0 mM CAPD-1 . The adsorption of CAPD derivatives on the CS interface follows the Langmuir isotherm model, including physisorption and chemisorption. Scanning electron microscopy (SEM) exploration confirmed the adsorption of the CAPD derivatives on the CS substrate. Monte Carlo (MC) simulations and DFT calculations revealed that the efficacy of the CAPD molecules correlates well with their structures, and this protection was attributed to their adsorption on the CS surface.

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Chalcone oxime derivatives as new inhibitors corrosion of carbon steel in 1 M HCl solution

Cited by 41 publications

References 67 publications

Performance Evaluation of New Chalcone Oxime Functionalized Graphene Oxide as a Corrosion Inhibitor for Carbon Steel in a Hydrochloric Acid Solution

Performance Evaluation of New Chalcone Oxime Functionalized Graphene Oxide as a Corrosion Inhibitor for Carbon Steel in a Hydrochloric Acid Solution

Adsorption and Inhibition Mechanisms of New Pyrazole Derivatives for Carbon Steel Corrosion in Hydrochloric Acid Solutions Based on Experimental, Computational, and Theoretical Calculations

Efficient Synthesis of 6,7-Dihydro-5H-cyclopenta[b]pyridine-3-carbonitrile Compounds and Their Applicability As Inhibitor Films for Steel Alloy Corrosion: Collective Computational and Practical Approaches

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Chalcone oxime derivatives as new inhibitors corrosion of carbon steel in 1 M HCl solution

Cited by 41 publications

References 67 publications

Performance Evaluation of New Chalcone Oxime Functionalized Graphene Oxide as a Corrosion Inhibitor for Carbon Steel in a Hydrochloric Acid Solution

Performance Evaluation of New Chalcone Oxime Functionalized Graphene Oxide as a Corrosion Inhibitor for Carbon Steel in a Hydrochloric Acid Solution

Adsorption and Inhibition Mechanisms of New Pyrazole Derivatives for Carbon Steel Corrosion in Hydrochloric Acid Solutions Based on Experimental, Computational, and Theoretical Calculations

Efficient Synthesis of 6,7-Dihydro-5H-cyclopenta[b]pyridine-3-carbonitrile Compounds and Their Applicability As Inhibitor Films for Steel Alloy Corrosion: Collective Computational and Practical Approaches

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Chalcone oxime derivatives as new inhibitors corrosion of carbon steel in 1 M HCl solution