Chalcogenide mechanochemistry in materials science: insight into synthesis and applications (a review)

Baláž, Peter; Baláž, Matěj; Achimovičová, Marcela; Bujňáková, Zdenka; Dutková, Erika

doi:10.1007/s10853-017-1174-7

Cited by 80 publications

(52 citation statements)

References 183 publications

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“…The contributions of mechanochemical methods to the field of magnetic and magnetocaloric materials are reviewed by Blazquez et al [4]; the article includes a detailed analysis of the effect of the reactants microstructure, final morphology, and compositional homogeneity of the particles in the magnetocaloric effect. Finally, the last review was written by Baláž et al [5] and represents a comprehensive account of the history and possibilities of mechanochemical methods in the synthesis of simple and complex chalcogenides. The article also includes some interesting applications in the fields of materials engineering, bioimaging, and cancer treatment and ends with a small section on the possibilities of scaling up the process.…”

Section: Methodsmentioning

confidence: 99%

Preface to the special section on mechanochemical synthesis

Fuentes

2017

J Mater Sci

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Section: Methodsmentioning

confidence: 99%

Preface to the special section on mechanochemical synthesis

Fuentes

2017

J Mater Sci

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“…Mechanochemistry has been extensively used recent in the synthesis of nanocrystalline binary, ternary and quaternary chalcogenides and their nanocomposites. 50 Within this field, Baláž et al demonstrated the large scale mechanochemical synthesis of potential chalcogenide solar cell absorbers based on quartenary sulphides. 51 The reaction was conducted using an industrial sized eccentric vibrational mill, in a 5 L milling chamber charged with 35 mm diameter tungsten carbide balls (Fig.…”

Section: Materials Containing P-block Elementsmentioning

confidence: 99%

Main group mechanochemistry: from curiosity to established protocols

2019

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In the last few decades, mechanochemistry has become rapidly established as a powerful tool enabling environmentally-benign and sustainable chemical syntheses. Not only have these techniques been demonstrated as viable alternatives to traditional solution-based syntheses, but they have also received attention for their ability to enable new reactivity and ''unlocking'' novel compounds inaccessible by conventional methods. Reflecting the rising popularity of mechanochemistry, many excellent reviews highlighting its benefits have recently been published. Whilst the scope of most of these focuses on organic chemistry, transition-metal catalysis, porous framework materials, coordination compounds and supramolecular synthesis, few have addressed the use of mechanochemical ball milling for the synthesis of compounds containing s-and p-block elements. This tutorial review turns the spotlight towards mechanochemical research in the field of inorganic main group chemistry, highlighting significant advantages that solid-state inorganic reactions often possess, and the potential for these to drive the development of greener methodologies within the modern main group arena. Key learning points(1) Mechanochemistry and its historical background.(2) Tools and parameters affecting mechanochemical syntheses. (3) Solid and liquid additives in mechanochemistry. (4) In situ vs. ex situ reaction monitoring. (5) Key examples of mechanochemically synthesised main group compounds and complexes.

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“…Recently, mechanochemistry (MC), as an effective and green technique, has attracted more and more attention owing to its high efficiency, facile operability, and environmental friendliness [22][23][24][25]. Significantly, it has demonstrated inestimable potentials in materials synthesis through solid-solid reactions, and especially exhibited ultra-high activation effect for the crystalline substance [26][27][28][29][30]. Therefore, MC may be used as a viable method for the synthesis of ACMs by using of CaC 2 as alkynyl source.…”

Section: Introductionmentioning

confidence: 99%

Efficient synthesis of alkynyl carbon materials derived from CaC2 through solvent-free mechanochemical strategy for supercapacitors

et al. 2019

SN Appl. Sci.

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The synthesis of new carbonaceous electrode materials for supercapacitors and the discovery of efficient techniques for the CaC 2 activation are meaningful subjects. In this study, unique alkynyl carbon materials (ACMs) were effectively synthesized through solvent-free mechanochemical reactions of CaC 2 with C 2 Cl 6 or C 6 Br 6. Their components and structure were comprehensively characterized, and their supercapacitor performances were examined in detail. The mechanochemistry has proved to be an efficient and targeted technique for the reactive activation of CaC 2. The sp-C dominated ACMs feature interconnected framework with hierarchical pores, tunable structures, and low cost of raw materials. As electrodes for supercapacitors, the ACMs exhibit high specific capacitances in the range of 48.4-132.4 F g −1 with excellent electrical conductivities and outstanding cycling stabilities. This work provides an efficient, green, and cost-effective strategy for the synthesis of ACMs from wildly available precursors, and a significant assistance for the renaissance of CaC 2 chemistry.

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Chalcogenide mechanochemistry in materials science: insight into synthesis and applications (a review)

Cited by 80 publications

References 183 publications

Preface to the special section on mechanochemical synthesis

Preface to the special section on mechanochemical synthesis

Main group mechanochemistry: from curiosity to established protocols

Efficient synthesis of alkynyl carbon materials derived from CaC2 through solvent-free mechanochemical strategy for supercapacitors

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