The chemical-looping combustion (CLC) technique with
an intrinsic
feature for carbon capture is playing a critical role in the industrial
process planning. As the key technology in CLC, the behaviors of oxygen
carriers with different weight ratios of NiO/CuO are investigated
using the two-fluid model in this work. The kinetic theory of granular
flow is employed for the description of particle motion, while the
EMMS model is used to clarify the effect of mesoscale structure on
gas–solid interaction in the fuel reactor. With the coexistence
of Ni and Cu in the oxygen carriers, a zero emission of H2 and CO is observed at the outlet of the fuel reactor, while the
intermediate products of H2 and CO arise in the system
with Ni-based oxygen carriers. The complete conversion of CH4 is observed in the fuel reactor with various components of Ni–Cu
oxygen carriers. The reactivity of CuO and NiO with gas fuel is analyzed,
and the equilibrium state in the CLC system with different weight
ratios of NiO/CuO is computed and compared. Moreover, different behaviors
of oxygen carriers with mechanical mixing of nickel oxide and copper
oxide are explored in the fuel reactor compared with that of Ni–Cu
oxygen carriers. In addition, the bubble disturbance leads to the
nonuniform distribution of reaction rate in the FR. The simulation
results indicate that the Ni4Cu12 oxygen carriers have the most vigorous
interaction with gas fuel, whereas the oxygen carriers with mechanical
mixing of metal oxides are not recommended in the CLC process. The
study assists in providing new insight into the understanding of oxygen
carriers in the CLC system.