CeRu<sub>2</sub>: Valence Change of Ce Ions Induced by Hydrogen Absorption

Tessema, G. X.; Peyrard, J.; Nemoz, A.; Senateur, J.P.; Rouault, Alain; Fruchart, R.

doi:10.1524/zpch.1979.116.116.209

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“…The magnetic data of Ce 16 Ru 9 [8] have been interpreted by different cerium valences. The Laves phase CeRu 2 becomes superconducting below 6.2 K [11][12][13][14]. This Ce-Ru bonding situation becomes more extreme in the ternary indides Ce 3 Ru 2 In 3 (238 and 273 pm Ce-Ru) [15], Ce 16 Ru 8 In 37 (237 pm CeRu) [16], Ce 2 Ru 2 In 3 (232 and 237 pm Ce-Ru) and Ce 3 Ru 2 In 2 (223 and 228 pm Ce-Ru) [17], CeRu 0.88 In 2 (253 pm Ce-Ru) [18] and CeRuAl (280-286 pm Ce-Ru) [19].…”

Section: Introductionmentioning

confidence: 99%