Scale-free networks are a type of complex networks in which the degree distribution of the nodes is according to the power law. In this chapter, the author uses the widely studied Barabasi-Albert (BA) model to simulate the evolution of scale-free networks and study the temporal variation of degree centrality, eigenvector centrality, closeness centrality, and betweenness centrality of the nodes during the evolution of a scale-free network according to the BA model. The model works by adding new nodes to the network, one at a time, with the new node connected to m of the currently existing nodes. Accordingly, nodes that have been in the network for a longer time have greater chances of acquiring more links and hence a larger degree centrality. While the degree centrality of the nodes has been observed to show a concave down pattern of increase with time, the temporal (time) variation of the other centrality measures has not been analyzed until now.