“…Indeed, the investigation of infiltrating waters permits to clarify the natural biogeochemical processes occurring in the vadose zone ecosystem, and to assess their ecological features in relation to potential anthropogenic impacts (Fairchild & Treble, 2009; Fehér et al, 2016; Hartland et al, 2012; Moldovan et al, 2007; Motyka et al, 2005). In particular, the analysis of dripping water allows to understand and reconstruct the processes leading to speleothem deposition, hence their use as significant paleoenvironmental archives (Baldini et al, 2006; Columbu et al, 2018, 2019, 2020, 2022; Fairchild et al, 2000; Fairchild & Baker, 2012; Fairchild & Treble, 2009; Lauritzen, 2018; Nava‐Fernandez et al, 2020; Riechelmann et al, 2013; Rossi & Lozano, 2016; Tremaine & Froelich, 2013; Wong et al, 2011). Indeed, several studies on cave waters have been, and still are, primarily focused on the ecohydrology of karst systems (Motyka et al, 2005; Nannoni et al, 2020), comprising the dissolution/precipitation processes (Fairchild & Baker, 2012) and the surface pollution sources affecting them (D'Angeli et al, 2017; Jiménez‐Sánchez et al, 2008; Mahler & Massei, 2007; Ruggieri et al, 2017).…”