2015
DOI: 10.1039/c5nr05511c
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Cellulose nanofibrils improve the properties of all-cellulose composites by the nano-reinforcement mechanism and nanofibril-induced crystallization

Abstract: All-cellulose nanocomposite films containing crystalline TEMPO-oxidized cellulose nanofibrils (TOCNs) of 0-1 wt% were fabricated by mixing aqueous TOCN dispersions with alkali/urea/cellulose (AUC) solutions at room temperature. The mixtures were cast on glass plates, soaked in an acid solution, and the regenerated gel-like films were washed with water and then dried. The TOCN did not form agglomerates in the composites, and had the structure of TOCN-COOH, forming hydrogen bonds with the hydroxyl groups of the … Show more

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Cited by 72 publications
(71 citation statements)
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“…It is noteworthy that cellulose nanocomposites are one of the most promising structures to the packaging field [11][12][13][14].…”
Section: Introductionmentioning
confidence: 99%
“…It is noteworthy that cellulose nanocomposites are one of the most promising structures to the packaging field [11][12][13][14].…”
Section: Introductionmentioning
confidence: 99%
“…Nishino c.s., [125,133] created transparent all-cellulose composites by partial surface dissolution of cellulose fibers, with dissolved fiber material filling the spaces between the fibers, creating strong and transparent composites ( Figure 7G-H). Research by Yano c.s., [134,157] Berglund c.s., [135][136][137] and others [158,159] reported transparent nanocomposite films based on bacterial cellulose and other forms of nanocellulose. Here, nanocellulose fibrous networks are typically impregnated with resins to introduce transparency.…”
Section: Mechanical Propertiesmentioning
confidence: 99%
“…NC films also show excellent oxygen barrier properties related to the high crystallinity, a network structure held together through strong inter- and intramolecular hydrogen bonds, a lamellar nanofiber structure, and dense fiber bundles [ 156 , 157 , 158 ]. CNFs have also been used as filler in all-cellulose nanocomposite films [ 139 , 159 ]. In addition, NC, as a dietary fiber, can be used in functional foods to reduce the risk of chronic diseases such as diabetes, obesity, cardiovascular disease, and diverticulitis.…”
Section: Market and Applicationsmentioning
confidence: 99%