Cellulose-based Li-ion batteries: a review

Jabbour, Lara; Bongiovanni, Roberta Maria; Chaussy, Didier; Gerbaldi, Claudio; Beneventi, Davide

doi:10.1007/s10570-013-9973-8

Cited by 265 publications

(170 citation statements)

References 146 publications

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“…[197][198][199] Although the cellulose paper has lower performance than the commercially implemented microporous polymer separators it is considered that its integration into the Li-ion battery value chain will lower the production costs and make the manufacturing process environmentally benign. [ 200,201 ] At the same time, the hygroscopic nature of cellulose based paper, the absence of a thermal shutdown effect and need of thicker paper to avoid dendrites growth through the large pores of the paper are some of the issues that must be solved before targeting large scale industrial implementation. [ 200 ] Cellulose papers have been already proposed as a building material for energy storage devices, especially in aqueous cells, where hygroscopicity is benefi cial for the cell operation.…”

Section: Wileyonlinelibrarycommentioning

confidence: 99%

“…[ 200,201 ] At the same time, the hygroscopic nature of cellulose based paper, the absence of a thermal shutdown effect and need of thicker paper to avoid dendrites growth through the large pores of the paper are some of the issues that must be solved before targeting large scale industrial implementation. [ 200 ] Cellulose papers have been already proposed as a building material for energy storage devices, especially in aqueous cells, where hygroscopicity is benefi cial for the cell operation. [ 202 ] It was primarily tested as a replacement solution for the electrolyte soaked separators.…”

Section: Wileyonlinelibrarycommentioning

confidence: 99%

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Design Considerations for Unconventional Electrochemical Energy Storage Architectures

Vlad

Singh

Galande

et al. 2015

Advanced Energy Materials

278

204

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all need to be used in conjugation with an energy storage system to provide smooth power leveling. Currently, electrochemical energy storage systems are by far the most optimal solutions for powering a broad range of technologies, expanding from compact and light-weighted portable electronic devices to stationary gridscale energy storage applications. [3][4][5][6] These energy storage devices (batteries and supercapacitors) store the available electrical energy in the form of chemical energy and release it whenever needed, by simply reversing the electrochemical reaction. [7][8][9][10][11] Among various available battery chemistries, lithium batteries and supercapacitors are the most promising technologies. [ 7,[9][10][11][12][13][14][15][16][17][18][19][20] Ever since the realization of the fi rst electrochemical energy storage cell by Alessandro Volta (end of 17th century), the working principle and its function has changed very little. [ 21,22 ] Basically, two redox couples (or charge storage electrodes), electrically and physically separated, are bridged by an ion conducting medium to constitute an electrochemical cell. This holds true also for modern Li-ion batteries, although the chemistry involved is much more complex. During operation, the electrons are transferred through an external circuit while ions shuttle through the electrolyte to counterbalance the depleted charge at the electrodes. [ 23 ] So far, much of the effort has been directed towards improvement of the energy and power characteristics by downsizing the active components, re-engineering the current collectors and separators, as well as fi ne-tuning the Batteries have become fundamental building blocks for the mobility of modern society. Continuous development of novel battery chemistries and electrode materials has nourished progress in building better batteries. Simultaneously, novel device form factors and designs with multi-functional components have been proposed, requiring batteries to not only integrate seamlessly to these devices, but to also be a multi-functional component for a multitude of applications. Thus, in the past decade, along with developments in the component materials, the focus has been shifting more and more towards novel fabrication processes, unconventional confi gurations, and additional functionalities. This work attempts to critically review the developments with respect to emerging electrochemical energy storage confi gurations, including, amongst others, paintable, transparent, fl exible, wire or cable shaped, ultra-thin and ultra-thick confi gurations, as well as hybrid energy storage-conversion, or graphene-incorporated batteries and supercapacitors. The performance requirements are elaborated together with the advantages, but also the limitations, with respect to established electrochemical energy storage technologies. Finally, challenges in developing novel materials with tailored properties that would allow such confi gurations, and in designing easier manufacturing techniques that can be widely adopted ar...

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Section: Wileyonlinelibrarycommentioning

confidence: 99%

Section: Wileyonlinelibrarycommentioning

confidence: 99%

Design Considerations for Unconventional Electrochemical Energy Storage Architectures

Vlad

Singh

Galande

et al. 2015

Advanced Energy Materials

278

204

View full text Add to dashboard Cite

show abstract

“…It is, thus, an excellent material for the production of cheap and eco-friendly devices. Over the last years, the cellulose and its derivatives have been intensively employed as binders of carbon-based electrodes of lithium-ion batteries as well as separators or electrolyte membranes of these devices [35][36][37][38]. Recently, the natural cellulose was also introduced as a green binder of the EDLC electrode, compatible with all kinds of electrolytes employable in EDLCs (aqueous, organic and ionic liquid electrolytes) [39][40][41].…”

Section: Introductionmentioning

confidence: 99%

Electrodes and hydrogel electrolytes based on cellulose: fabrication and characterization as EDLC components

Kasprzak

Stępniak

Galiński

2018

J Solid State Electrochem

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In the present work, the cellulose-based materials were manufactured and used as components of electrochemical double layer capacitors (EDLCs). The preparation method of cellulose membranes as well as composite electrodes containing cellulose as a binder was presented. These materials were prepared using for the first time ionic liquid/dimethyl sulfoxide (IL/DMSO) mixture solvent. Obtained components displayed a uniform structure, thermal stability, and good electrochemical properties. The electrochemical performances of these materials were studied in 2-electrode EDLC cells by common electrochemical techniques as cyclic voltammetry (CV), galvanostatic charge/discharge (GCD), and electrochemical impedance spectroscopy (EIS). The composite electrodes were investigated in three types of electrolytes: aqueous, organic, and ionic liquids. The cellulose membranes were, however, soaked in an aqueous electrolyte and tested as hydrogel polymer electrolytes. All investigated materials show high efficiency in terms of specific capacity. The studied cellulose-based capacitors exhibited specific capacitance values in the range of 20-22 F g −1 , depending on the type of applied electrolyte.

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“…carbon nanotubes as conductors and electrodes [11], silicon nanowires as anodes [12], and cellulose-which is the most abundant renewable polymer source available-as a substrate for electrode materials [13][14][15]. Thus, prominent trends in the research of power sources include miniaturization (introduction of low-scale materials such as nanoparticles or graphene) and the achievement of high flexibility in combination with the abundance, non-toxicity, and eco-friendliness mentioned earlier [11][12][13][14][15][16][17][18]. This work deals with the fabrication of an ultra-thin battery composed of a film of silicon nanoparticles encased between two aluminium planar electrodes.…”

Section: Methodsmentioning

confidence: 99%

Spontaneous Generation of Electromotive Force in Thin Film Al/Nanosilicon/Al Structures

et al. 2017

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Contemporary pursuits in electronics include the miniaturization as well as flexibilization of devices. Although there are a large number of different thin and flexible electrochemical batteries, only a few can boast the possibility of working in high humidity conditions. This paper reports on the fabrication of structures consisting of films of silicon nanoparticles encased between two aluminium electrodes. The value of electromotive force (emf) measured depends on the temperature of the sample and on the pressure of water vapor in the storage atmosphere and reaches approximately 1 V. Volt-ampere characteristics were investigated at different conditions to yield a model of emf generation in these structures. It was found that the reaction of water with silicon nanoparticles is the prime reason behind emf generation. Such a source may be introduced into electronic paper, and employed in the next generation of smart cards. The structure may also be manufactured directly on the surface of silicon chips, such as on the back of crystals in microschemes.

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Cellulose-based Li-ion batteries: a review

Cited by 265 publications

References 146 publications

Design Considerations for Unconventional Electrochemical Energy Storage Architectures

Design Considerations for Unconventional Electrochemical Energy Storage Architectures

Electrodes and hydrogel electrolytes based on cellulose: fabrication and characterization as EDLC components

Spontaneous Generation of Electromotive Force in Thin Film Al/Nanosilicon/Al Structures

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