Ce:YAG transparent ceramics based on nanopowders produced by laser ablation method: Fabrication, optical and scintillation properties

Abstract

Transparent Ce:YAG ceramics were fabricated by the solid-state reaction method with an additional round of pre-calcining using nanopowders of Ce 2x Y 2−2x O 3 (x = 0.001, 0.01, 0.03 and 0.05) and Al 2 O 3 synthesized by laser ablation. Additional pre-calcining of the nanopowder mixture in air was used to partially transform the oxides into the YAG phase before sintering. The transmittance of the obtained 2-mm-thick Ce:YAG ceramics was over 81 % in the wavelength range of 500-900 nm. The average volumes of the scattering centers in the obtained ceramics were evaluated by direct count method to be 34, 74, 53, 50 ppm for 0.1, 1, 3 and 5 % Ce doping concentration, respectively. The absolute light yields, energy resolutions under 662 keV gamma ray, and decay curves of scintillations of the fabricated Ce:YAG samples were measured and compared to those of Ce:YAG and CsI:Tl single crystals.

Effect of Ce3+ Content and Annealing Temperature on the Optical and Scintillation Properties of Ce3+‐Doped Y3Al5O12 Nanoscintillator Synthesized by Sol–Gel Route

“…However, in inorganic matrices, prepared by sol–gel method, the synthesized optically opaque gel reduces significantly scintillation output. Furthermore, successfully preparing YAG:Ce 3+ nanocrystalline scintillator powders can be used to fabricate the same phosphor in transparent ceramic form, [ 15 ] which can replace single crystals. In addition, the new generation of scintillation detectors designed to be applied in devices for medical diagnostics, safety inspections, and radiation monitoring of nuclear reactors are based on nanoscintillators powders.…”