CCCLXXXIX.—The action of hydrogen sulphide on lithium ethoxide. Lithium hydrosulphide

Facile Synthesis of Lithium Sulfide Nanocrystals for Use in Advanced Rechargeable Batteries

“…We believe that this is because LiHS fully dissolves in DME and exists in some unknown complex form. For example, it is known that LiHS cannot precipitate out of ethanol but forms a LiHS/ethanol complex . The comparison with our previous work indicates that LiHS has higher solubility/complexity in DME than NaHS .…”

Metallic Salts of Alcohols and Alcohol Analogs.

“…Upon other occasions it is the by-product which is insoluble; sodium chloride is precipitated from alcohol in the synthesis of ferric ethoxide (377), FeCU + 3NaOC2H6 -> Fe(OC2H6)3 + 3NaCl chromic ethoxide (375), lithium ethoxide (197), and others (267). Corresponding metatheses in the methane and the ammonia systems enabled Schlenk and Holtz (333,334) to obtain some remarkable ammonium salts of hydrocarbons (CH3)4NC1 + (C6H6)3CNa -* (CH3)4NC(C6H6)3 + NaCl and amines.…”

“…Even sodium alkyls are reported valuable for preparing salts of alkylated acetonitriles (186), and aluminum alkoxides for manufacturing aluminum carboxylates (187). Exceptionally pure salts of inorganic acids are similarly accessible; hydrogen sulfide (317,197,312) and hydrogen selenide (387, 21) form hydrosulfides and hydroselenides of alkali metals, H2S + NaOC2H6 -* NaSH + C2H6OH…”