Cavity ring-down spectroscopy of the A 2Π3/2–X 2Π3/2 transition of BrO

The Rotational Spectra, Isotopically Independent Parameters, and Interatomic Potentials for the X12Π3/2 and X22Π1/2 States of BrO

“…This is not incorporated into the fit, but the influence of imperfect spatial overlap on the calculated value of ␥ can be estimated. The quantity [10] may be calculated from the Dunham potentials described above. For v ϭ 0, S 0,0 ϭ 0.99657.…”

“…Loewenschuss et al (8) had independently suggested the revised numbering based on an analysis of the matrix isolation spectrum. Recent measurements of the A-X spectrum with Fourier transform spectroscopy (9) and cavity ringdown spectroscopy (10) have confirmed that the predissociation linewidths limit the effective resolution of the spectrum to 1 cm Ϫ1 . The BrO ground electronic state has been characterized in considerably greater detail.…”

Environmental effects of large igneous province magmatism: a Siberian perspective

“…Cl + CH 2 FCF 3 (HFC-134a). The recommended value for k(298 K) is an average of the results from the relative rate studies of Wallington and Hurley [1404], Tuazon et al [1326], and Kaiser [684] and from the absolute rate study of Louis et al [846], which is assumed to supercede the earlier study by Sawerysyn et al [1151]. [1427] and the relative rate studies of Wallington and Hurley [1404] and Tuazon et al [1326] each recalculated based on the current recommendation for the rate constant of the appropriate reference reaction.…”

Cavity ring-down study of BrO radicals: Kinetics of the Br + O3 reaction and rate of relaxation of vibrationally excited BrO by collisions with N2 and O2

“…The formation of BrO radicals was monitored using their absorption at 338.3 -340.1 nm, A-X(7,0) band [29]. The concentration of BrO was monitored by the tuning wavelength of the dye laser at 338.5 nm.…”