“…Grain refinement and structure modification by ultrasound have already been widely suggested in the past [54,55], although most of the works available in the literature related to electrodeposited Ni coatings only show either some evidence of the grain refinement effect by ultrasound on the surface of the coatings [20,56,57] or did not show any real evidence at all [19]. Regarding this, Lampke et al's backscattered electron beam diffraction (EBSD) results showed that, whereas large Ni crystals were still noticeable in Ni deposits produced under ultrasound, many small crystals could be observed, resulting in an overall grain refinement when compared with Ni coatings electrodeposited in the absence of ultrasound [58]. A very similar effect in the grain structure was observed in the present study, as the use of ultrasound during the electrodeposition, particularly at high powers, resulted in a more fragmented structure where columnar crystals were observed alternating with very small grains.…”