Cationic photoinitiated copolymerization of 1-propenyl–vinyl ether systems

Isomerization of alkyl allyl and allyl silyl ethers catalyzed by ruthenium complexes

“…Cationic photopolymerized 1-propenyl ethers are of increasing importance in many industrial fields, particularly in production of various protecting and decorative coatings, inks, adhesives [1][2][3]. Synthesis of 1-propenyl ethers might be easily achieved by isomerization of allyl ethers in the presence of bases [4,5] and various transition metal complexes [6][7][8][9].…”

Co-polymerization of Isobutyl/4-Hydroxybutyl Vinyl Ether and Maleic Anhydride

“…3, the peaks at 2.5 (2H, CH from MA), 1.65 (2H, CH 2 from IBVE), 1.2 (1H, CH from IBVE) and 0.86 (6H, CH 3 from IBVE) ppm were quite clear. From this data we can confirm that the co-polymer does not have any double bonds, and that the co-polymer probably was alternating [5,8]. Analysis of the methylene of the polymer chain was achieved by the typical procedure reported by Hao and Fujimori [2].…”

“…Research on the co-polymerization of MA and other alkyl vinyl ethers is becoming one of the most active research fields because of their unique properties and wide range of applications such as adhesives, photo-cross-linkable and photosetting resin compositions, as well as controlled-release coatings, medicinal tablet coatings and so forth [1][2][3][4][5]. Through co-polymerization polymers with different structures and significant properties can be obtained.…”

Temperature controlled cationic photo-curing of a thick, dark composite

“…In contrast, alkyl diglycidyl ethers displayed a long induction period. 3,9,15 The studies showed that vinyl substituted epoxides markedly accelerated the cationic ringopening photopolymerization of oxetane monomers with the addition of small amounts (3-5 wt%) of the epoxide to the oxetane monomer.…”