Cationic palladium(II)–acetylacetonate complexes bearing pyridinyl imine ligands as catalysts for the hydroamination of phenylacetylene and polymerization of norbornene

Suslov, D. S.; Suchkova, Anastasia V.; Bykov, M. V.; Abramov, Z. D.; Pakhomova, M. V.; Orlov, T. S.; Ushakov, Igor А.; Bоrodinа, Tatyana N.; Смирнов, В. И.

doi:10.1016/j.mencom.2023.02.011

Cited by 1 publication

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“…Chen et al and Suslov et al evaluated Pd complexes bearing a hemilabile bidentate α-amino-pyridine moiety (Pd90 and Pd91, Figure 19) in norbornene polymerization. [88,89] Acetylacetonate Pd complexes (Pd91) did not catalyze the VAP of NB without a cocatalyst. However, oligomerization of NB was observed in the presence of methylpalladium complexes with a labile MeCN ligand (Pd90).…”

Section: Palladium Complexes Containing Chelate Bidentate Nnligandsmentioning

confidence: 99%

Single‐Component Catalysts for the Vinyl‐Addition Polymerization of Norbornene and its Derivatives

Bermesheva,

Bermeshev

2023

ChemCatChem

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Vinyl‐addition polynorbornenes are versatile templates for the targeted design of high‐performance materials for various applications, such as membrane gas separation, micro‐ and optoelectronics, fuel cells, sensors, catalyst supports, etc. The cornerstone of the syntheses of these compounds is the choice of a catalyst for polymerization. Considering valuable developments in the field of catalysts for vinyl‐addition polymerization (VAP) summarized in previously published reviews, mention should be made that the research efforts were largely focused on two‐ and three‐component catalytic systems that suffer from the need to use a cocatalyst. The aim of this review is to highlight the advances in the design and development of single‐component catalysts for the VAP of norbornenes. Such catalysts are categorized into two main groups, viz., neutral and cationic catalysts. The catalyst structure, the catalytic activity, and the molecular weight characteristics of polymers produced on these catalysts are considered in detail. We believe this article can serve as a guide for developing future catalysts to gain access to new functional materials.

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Section: Palladium Complexes Containing Chelate Bidentate Nnligandsmentioning

confidence: 99%

Single‐Component Catalysts for the Vinyl‐Addition Polymerization of Norbornene and its Derivatives

Bermesheva,

Bermeshev

2023

ChemCatChem

View full text Add to dashboard Cite

show abstract

Cationic palladium(II)–acetylacetonate complexes bearing pyridinyl imine ligands as catalysts for the hydroamination of phenylacetylene and polymerization of norbornene

Cited by 1 publication

References 41 publications

Single‐Component Catalysts for the Vinyl‐Addition Polymerization of Norbornene and its Derivatives

Single‐Component Catalysts for the Vinyl‐Addition Polymerization of Norbornene and its Derivatives

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