2023
DOI: 10.1016/j.jcis.2022.09.078
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Cationic doping induced sulfur vacancy formation in polyionic sulfide for enhanced electromagnetic wave absorption

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Cited by 29 publications
(8 citation statements)
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“…[27] These structural defects alter the rehybridized electron orbitals and bond lengths by inducing Gaussian curvature in situ, possibly leading to a stronger electron redistribution than doping. [28] The study of defects acting on MA is an emerging subdivision field, but unfortunately still retains in the preliminary understanding, e.g., anion/cation vacancies, [29,30] defect concentration, [31] etc. Compared with in situ doping, ex situ doping, like an intruder, always forces the target subject to accept itself through postprocessing technology.…”
Section: Introductionmentioning
confidence: 99%
“…[27] These structural defects alter the rehybridized electron orbitals and bond lengths by inducing Gaussian curvature in situ, possibly leading to a stronger electron redistribution than doping. [28] The study of defects acting on MA is an emerging subdivision field, but unfortunately still retains in the preliminary understanding, e.g., anion/cation vacancies, [29,30] defect concentration, [31] etc. Compared with in situ doping, ex situ doping, like an intruder, always forces the target subject to accept itself through postprocessing technology.…”
Section: Introductionmentioning
confidence: 99%
“…S2, ESI†) confirmed that the Ni x S y @De samples obtained after sulfurization contained a large number of sulfide vacancies. 35 The high-angle annular dark-field scanning transmission electron microscopy-energy-dispersive X-ray spectroscopy (HAADF-EDS) image shown in Fig. 3f reveals that Ni x S y @De is composed of Ni, S, O, and Si elements, further confirming the successful sulfurization process.…”
Section: Discussionmentioning
confidence: 78%
“…S2, ESI †) confirmed that the Ni x S y @De samples obtained after sulfurization contained a large number of sulfide vacancies. 35 The high-angle annular dark-field scanning transmission electron microscopy-energy-dispersive X-ray spectroscopy (HAADF-EDS) image shown in Fig. 3f 41 Furthermore, the chemical bond types within these three samples were investigated in greater detail through FTIR spectroscopy.…”
Section: Discussionmentioning
confidence: 99%
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“…When analyses of VP were found to include carbon at a concentration of 61.07 percent, hydrogen at 11.22 percent, oxygen at 23.17 percent, nitrogen at 1.39 percent, and sulfur at 3.15 percent, according to the results of elemental analysis [15]. Because sulfur groups are weak bases and have a chemical affinity for heavy metals, the presence of sulfur in VP enables us to consider it as a candidate for use as an adsorbent [16]. Figure 1 presents the FT-IR spectrum of VP.…”
Section: Evaluation Of the Vp Adsorbent's Propertiesmentioning
confidence: 99%