Cathodic electropolymerization of methacrylonitrile studied in situ by quartz crystal microbalance, cyclic voltammetry, and impedance spectroscopy

Tanguy, J.; Deniau, Guy; Zalczer, G.; Lecayon, G.

doi:10.1016/s0022-0728(96)04743-2

Cited by 28 publications

(21 citation statements)

References 23 publications

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“…The alternative hypothesis that a highly cross-linked and insoluble polymer precipitates on the surface of the electrode was also considered. [36] It was, however, ruled out by several experimental observations:…”

Section: Grafted Versus Nongrafted Films: Film Thicknessmentioning

confidence: 99%

Molecule‐to‐Metal Bonds: Electrografting Polymers on Conducting Surfaces

Palacin¹,

Bureau²,

Charlier³

et al. 2004

ChemPhysChem

124

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Electrografting is a powerful and versatile technique for modifying and decorating conducting surfaces with organic matter. Mainly based on the electro-induced polymerization of dissolved electro-active monomers on metallic or semiconducting surfaces, it finds applications in various fields including biocompatibility, protection against corrosion, lubrication, soldering, functionalization, adhesion, and template chemistry. Starting from experimental observations, this Review highlights the mechanism of the formation of covalent metal-carbon bonds by electro-induced processes, together with major applications such as derivatization of conducting surfaces with biomolecules that can be used in biosensing, lubrication of low-level electrical contacts, reversible trapping of ionic waste on reactive electrografted surfaces as an alternative to ion-exchange resins, and localized modification of conducting surfaces, a one-step process providing submicrometer grafted areas and which is used in microelectronics.

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Section: Grafted Versus Nongrafted Films: Film Thicknessmentioning

confidence: 99%

Molecule‐to‐Metal Bonds: Electrografting Polymers on Conducting Surfaces

Palacin¹,

Bureau²,

Charlier³

et al. 2004

ChemPhysChem

124

View full text Add to dashboard Cite

show abstract

“…It has been shown previously that thickness and grafting density are actually correlated, each additional cycle both thickening and making the film denser [20] and more impervious to further penetration by new monomers. It is thus not surprising to find an optimum value for the number of cycles, as a compromise between the thickening and the densification of the grafted film.…”

Section: Influence Of the Voltammetric Parameters On The Film Thicknessmentioning

confidence: 86%

Comparison of two “grafting from” techniques for surface functionalization: Cathodic electrografting and surface-initiated atom transfer radical polymerization

Mouanda¹,

Bassa²,

Deniau³

et al. 2009

Journal of Electroanalytical Chemistry

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“…Then they analyzed the rotating disk electrode surface by X-ray photoelectron spectroscopy (XPS) and ellipsometry at the end of the experiment. In the same procedure, (Tanguy, Deniau, Zalczer & Lécayon, 1996) suggested that the use of a rotating disk electrode (RDE) spinning at a very high rotation rate could provide interesting information towards deciding which mechanism is the most feasible. Rotating disk electrode voltammetry has been shown to be a fast, inexpensive, and simple technique for studying substrate kinetics at mutant catecholamine and wild-type transporters.…”

Section: Rotating Disk Electrode Apparatusmentioning

confidence: 99%

Rotating Disk Apparatus: Types, Developments and Future Applications

Rashed¹,

Abdulbari²,

Salleh³

et al. 2016

MAS

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Power consumption reduction investigations attracted the attention of enormous numbers of researchers in the past few decades due to its high academic and economic impacts. The pumping power losses during the transportation of crude oils are considered as one of the main power consuming applications due to the turbulent mode of transportation. Investigating the possible solutions for this problem is expensive and time consuming due to the large apparatuses needed to simulate the flow in real pipelines. Rotating disk apparatus (RDA) is an instrument mainly comprising a rotating disk and an electrical motor to rotate the disk, which was implemented as an efficient and economical path to simulate what can be done in pipelines through generating a controlled degree of turbulence. This technique was also used in many other scientific applications due to its dynamic mode of operation. For example, a rotating disk electrode was used in electrodeposition processes and to characterize deposition film thickness and uniformity. The rotating disk reactor was employed to investigate the reaction rate between fluids and solid surfaces. The present work evaluates the RDA from different prospective and applications in order to introduce it as an efficient research tools for future dynamic investigations.

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Cathodic electropolymerization of methacrylonitrile studied in situ by quartz crystal microbalance, cyclic voltammetry, and impedance spectroscopy

Cited by 28 publications

References 23 publications

Molecule‐to‐Metal Bonds: Electrografting Polymers on Conducting Surfaces

Molecule‐to‐Metal Bonds: Electrografting Polymers on Conducting Surfaces

Comparison of two “grafting from” techniques for surface functionalization: Cathodic electrografting and surface-initiated atom transfer radical polymerization

Rotating Disk Apparatus: Types, Developments and Future Applications

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