2020
DOI: 10.1002/jccs.201900383
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Catechol oxidase and phenoxazinone synthase mimicking activity, X‐ray diffraction and density function theory study of pyridine and phenolate‐based manganese(II) and iron(III) complexes: Synthesis and spectroscopic characterization

Abstract: A new series of MnII and FeIII chelates containing pyridine and phenolate‐based ligands was synthesized by treating the metal salt in ethanol with the Schiff‐bases, which were formed in situ. Analytical (C, H, N, and M), thermal analysis (thermogravimetric analysis & differential thermogravimetric), and spectroscopic techniques (IR, UV–Vis, ESR) in addition to molar conductance and magnetic measurements were employed to characterize the prepared metal chelates. Mono‐nuclear metal complexes, with N5 donor conta… Show more

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Cited by 5 publications
(5 citation statements)
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“…Nowadays, XRD data processing of microcrystalline samples of metallic complexes by Expo 2014 combined with Rietveld's method 55 has become an alternative technique for X-ray single crystal structural analysis. 7,26,27,56…”
Section: Resultsmentioning
confidence: 99%
See 4 more Smart Citations
“…Nowadays, XRD data processing of microcrystalline samples of metallic complexes by Expo 2014 combined with Rietveld's method 55 has become an alternative technique for X-ray single crystal structural analysis. 7,26,27,56…”
Section: Resultsmentioning
confidence: 99%
“…The computed values (Table 6) of cell dimensions such as a , b and c in Å and α , β and γ in (°), cell volume (Å 3 ), density (g cm −3 ) and Rietveld results are acceptable and comparable with those reported for similar cases. 7,26,27,56…”
Section: Resultsmentioning
confidence: 99%
See 3 more Smart Citations